Preparation of high performance blended cements and reclamation of iron concentrate from basic oxygen furnace steel slag

Abstract Basic oxygen furnace steel slag (BOFS) is a by-product of steel-making process that has rarely been utilized in the past and is usually deposited as waste. BOFS fractions with different size were characterized in terms of chemical and mineral compositions, cementitious activity, autoclave soundness and activity index in the present study. The results show that silicates and iron concentrate are inclined to exist in fine and coarse BOFS fractions, respectively. Fine BOFS fractions also present qualified autoclave soundness, high cementitious activity and strength contribution. Iron concentrate, containing about 60% Fe2O3, can be reclaimed from BOFS through a new approach proposed. Blended cements with 30–60% residual slag product have comparable properties with Portland cement. The approach is very helpful to conserve natural resources and energy, achieve cost saving and reduce CO2 emissions.

[1]  A Bandopadhyay,et al.  Innovative methodologies for the utilisation of wastes from metallurgical and allied industries , 2006 .

[2]  H Motz,et al.  Products of steel slags an opportunity to save natural resources. , 2001, Waste management.

[3]  V. N. Misra,et al.  An overview of utilization of slag and sludge from steel industries , 2007 .

[4]  Jueshi Qian,et al.  High performance cementing materials from industrial slags — a review , 2000 .

[5]  E Forssberg,et al.  An overview of recovery of metals from slags. , 2003, Waste management.

[6]  C. Shi Characteristics and cementitious properties of ladle slag fines from steel production , 2002 .

[7]  Joo-Hwa Tay,et al.  Autoclave properties of kirschsteinite-based steel slag , 2002 .

[8]  S. Tsivilis,et al.  Properties and hydration of blended cements with steelmaking slag , 2007 .

[9]  T. Mingshu,et al.  Durability study of steel slag cement , 1997 .

[10]  Frank Winnefeld,et al.  Effect of temperature on the pore solution, microstructure and hydration products of Portland cement pastes , 2007 .

[11]  T.S. Zhang,et al.  Factors influencing the properties of a steel slag composite cement , 2008 .

[12]  I. Altun,et al.  Study on steel furnace slags with high MgO as additive in Portland cement , 2002 .

[13]  Qijun Yu,et al.  Structural characteristics and hydration kinetics of modified steel slag , 2011 .

[14]  Ángel Rodríguez,et al.  Strength and workability of masonry mortars manufactured with ladle furnace slag , 2009 .

[15]  C. Shi,et al.  Early strength development and hydration of alkali-activated blast furnace slag/fly ash blends , 1999 .

[16]  Tongsheng Zhang,et al.  Effects of size fraction on composition and fundamental properties of Portland cement , 2011 .

[17]  C. Shi Steel Slag—Its Production, Processing, Characteristics, and Cementitious Properties , 2004 .