2-(Mesitylmethylsulfanyl)pyridine N-oxide monohydrate

In the title compound, C15H17NOS·H2O, the benzene and pyridine rings form a dihedral angle of 71.18 (2)°. The intramolecular S⋯O distance [2.737 (3) Å] is shorter than expected and, in terms of hybridization principles, the N—C—S angle [114.1 (2)°] is smaller than expected. The crystal structure is stabilized by intermolecular O—H⋯O and weak C—H⋯O hydrogen bonds. In addition, weak π–π stacking interactions with a centroid–centroid distance of 3.778 (3) Å are also observed.

[1]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[2]  G. Gattow,et al.  Kristallographische Computer-Programme für die CDC-3300. , 1971 .

[3]  G. Sheldrick A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[4]  Anthony L. Spek,et al.  Journal of , 1993 .

[5]  S. Hecht,et al.  DNA cleavage by oxygen radicals produced in the absence of metal ions or light , 1991 .

[6]  Dieter Schollmeyer,et al.  2,2′-[2,3,5,6-Tetramethyl-p-phenylenebis(methylenethio)]bis(pyridine N-oxide) , 2008, Acta crystallographica. Section E, Structure reports online.

[7]  Olga Kennard,et al.  Tables of bond lengths determined by X-ray and neutron diffraction. Part 1. Bond lengths in organic compounds , 1987 .