Transition-state theory for tunneling in dissipative media.

The recently developed theory for tunneling in dissipative systems is rederived using quantal transition-state theory. As predicted by Caldeira and Leggett, we find an exponential damping of the tunneling rate at 0 K. The exponential rate enhancement at low temperatures as well as the crossover temperature are also obtained with this approach. Moreover, the rate enhancement is given explicitly in terms of energy transfer from the bath to the dissociative mode. The present derivation includes memory effects.