A Novel Boron Oxide Organic Open-Framework Compound: B6O9(en)2@(H2en)Cl2

A new boron oxide organic open-framework compound with (H2en)Cl2 as a template was synthesized solvothermally and characterized by various techniques such as elemental analysis, IR spectroscopy, X-ray diffraction, thermogravimetric analysis, and luminescence. The framework is built up from neutral [B6O9] layers linked by ethylenediamine molecules through coordinative B–N bonds.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

[1]  Huan-xin Liu,et al.  Synthesis, crystal structure and NLO property of a nonmetal pentaborate [C6H13N2][B5O6(OH)4] , 2008 .

[2]  C. Knobler,et al.  Synthesis and structure of a new heptaborate oxoanion isomer: B7O9(OH)5(2-). , 2008, Inorganic chemistry.

[3]  C. Knobler,et al.  Crystalline alcoholamine borates and the triborate monoanion. , 2008, Inorganic chemistry.

[4]  Jianhua Lin,et al.  Synthesis and structure of a 1,6-hexyldiamine heptaborate, [H3N(CH2)6NH3][B7O10(OH)3] , 2007 .

[5]  Jianhua Lin,et al.  Synthesis and structure of [C2H10N2][B5O8(OH)]: A nonmetal pentaborate with nonlinear optical properties , 2007 .

[6]  Gang Xu,et al.  A white-light-emitting borate-based inorganic-organic hybrid open framework. , 2007, Angewandte Chemie.

[7]  Shoutian Zheng,et al.  [NH3CH2CHCH3NH3]][B8O11(OH)4]·H2O: Synthesis and characterization of the first 1D borate templated by 1,2-diaminopropane , 2007 .

[8]  Guo-Ming Wang,et al.  Syntheses, Characterizations, and Crystal Structures of Two New Organically Templated Borates , 2007 .

[9]  Changfeng Wu,et al.  A study of the luminescence properties of Eu3+-doped borate crystal and glass , 2007 .

[10]  Shoutian Zheng,et al.  B3O4(OH) · 0.5(C4H10N2): First organic–inorganic hybrid borate with a neutral layered framework , 2007 .

[11]  Hengzhen Shi,et al.  (NH3CH2CH2NH3)B6O9(OH)2 : Synthesis and crystal structure of a novel layered borate templated by ethylenediamine , 2006 .

[12]  Yi-Zhe Yu,et al.  Ba4Ga2B8O18Cl2.NaCl: a new polar structure with NaCl inclusion. , 2006, Inorganic chemistry.

[13]  W. Cheng,et al.  Se2(B2O7): a new type of second-order NLO material. , 2006, Journal of the American Chemical Society.

[14]  Jonathan J. Owen,et al.  Structures of Self-Assembled Nonmetal Borates Derived from α,ω-Diaminoalkanes , 2006 .

[15]  Zhi-Hong Liu,et al.  Two new borates containing the first examples of large isolated polyborate anions: chain [B7O9(OH)5]2- and ring [B14O20(OH)6]4-. , 2006, Inorganic chemistry.

[16]  Guo-Ming Wang,et al.  Syntheses and crystal structures of two new organically templated borates , 2004 .

[17]  Nicolas Penin,et al.  Borates: a survey of main trends concerning crystal-chemistry, polymorphism and dehydration process of alkaline and pseudo-alkaline borates , 2003 .

[18]  Masashi Yoshimura,et al.  Recent development of nonlinear optical borate crystals: key materials for generation of visible and UV light , 2000 .

[19]  C. Knobler,et al.  Guanidinium and imidazolium borates containing the first examples of an isolated nonaborate oxoanion: [B9O12(OH)6]3-. , 2000, Inorganic chemistry.

[20]  J. D. Grice,et al.  BORATE MINERALS. II. A HIERARCHY OF STRUCTURES BASED UPON THE BORATE FUNDAMENTAL BUILDING BLOCK , 1999 .

[21]  T. Jüstel,et al.  New Developments in the Field of Luminescent Materials for Lighting and Displays. , 1998, Angewandte Chemie.

[22]  P. Burns Borate clusters and fundamental building blocks containing four polyhedra; why few clusters are utilized as fundamental building blocks of structures , 1995 .

[23]  Joel D. Grice,et al.  Borate minerals; I, Polyhedral clusters and fundamental building blocks , 1995 .

[24]  Baichang Wu,et al.  Design and synthesis of an ultraviolet-transparent nonlinear optical crystal Sr2Be2B2O7 , 1995, Nature.

[25]  G. Heller A survey of structural types of borates and polyborates , 1986 .

[26]  E. Macherauch,et al.  Recent German activities in the field of x-ray stress analysis☆ , 1977 .

[27]  C. Christ,et al.  A crystal-chemical classification of borate structures with emphasis on hydrated borates , 1977 .