Properties of chitosan films prepared under different drying conditions

Abstract Chitosan-based packaging films were prepared by employing wet casting followed by two methods of drying at 80, 90 and 100 °C, viz, oven drying (OD) and infrared drying (ID), and the film properties were compared with those prepared under ambient temperature drying (AD ∼ 27 °C). Thin layer drying protocols were developed to explain convective oven drying and radiative infrared drying and characteristic constants were determined. IR drying was found to be more efficient and uniform than OD. The latter showed a higher colour index, compared to ID and AD films. Tensile strength of ID films (49.58–52.34 MPa) was less than that of AD films (56.78–59.38 MPa), while percent elongation of the former was reduced by only ∼1%. No significant differences were observed in their burst strength values. Water vapour and oxygen transmission rate values were slightly reduced in OD and ID films compared to those of AD films. X-ray diffraction pattern of OD films showed a different crystallinity nature.

[1]  M. N. Ramesh,et al.  Drying studies of cooked rice in a vibrofluidised bed drier. , 1996 .

[2]  R. Tharanathan,et al.  Functional packaging properties of chitosan films , 1998 .

[3]  F. W. Bakker-Arkema,et al.  Drying cereal grains , 1974 .

[4]  M. N. Ramesh,et al.  Influence of processing parameters on the drying of spice paprika , 2001 .

[5]  K. Ogawa Effect of Heating an Aqueous Suspension of Chitosan on the Crystallinity and Polymorphs , 1991 .

[6]  J. M. Bunn,et al.  Drying Rate Constants for Yellow Dent Corn as Affected by Fatty Acid Ester Treatments , 1993 .

[7]  H. Blair,et al.  Chitosan and modified chitosan membranes I. Preparation and characterisation , 1987 .

[8]  Y. Doi,et al.  Production of copolyesters of 3-hydroxybutyrate and 3-hydroxyvalerate by Alcaligenes eutrophus from butyric and pentanoic acids , 1988, Applied Microbiology and Biotechnology.

[9]  T. Rumsey,et al.  DRYING RATE EFFECT ON THE PROPERTIES OF WHEY PROTEIN FILMS , 1998 .

[10]  O. Fennema,et al.  THE EFFECTS of SOLUTION COMPOSITION and DRYING TEMPERATURE ON CRYSTALLINITY, PERMEABILITY and MECHANICAL PROPERTIES of METHYLCELLULOSE FILMS , 1993 .

[11]  G. Torri,et al.  Alkaline N-deacetylation of chitin enhanced by flash treatments. Reaction kinetics and structure modifications , 1990 .

[12]  Feng Chen,et al.  Drying of American ginseng (Panax quinquefolium roots by microwave-hot air combination , 1998 .

[13]  J. M. Bunn,et al.  Water Vapor Transmission Rates and Sorption Behavior of Chitosan Films , 2000 .

[14]  M. Rinaudo,et al.  Characterization of chitosan. Influence of ionic strength and degree of acetylation on chain expansion. , 1993, International journal of biological macromolecules.

[15]  R. Muzzarelli,et al.  Removal of trace metal ions from industrial waters, nuclear effluents and drinking water, with the aid of cross-linked N-carboxymethyl chitosan , 1989 .

[16]  C. Huei Effect of molecular weight of chitosan with the same degree of deacetylation on the thermal, mechanical, and permeability properties of the prepared membrane , 1996 .

[17]  A. Kaya,et al.  Microwave drying effects on properties of whey protein isolate edible films , 2000 .

[18]  N. Gontard,et al.  Prolongation of the Shelf-life of Perishable Food Products using Biodegradable Films and Coatings , 1996 .

[19]  M. Yokoyama,et al.  Melting temperatures of thermally reversible gels IV. Methyl cellulose-water gels , 1978 .

[20]  G. E. Page,et al.  FACTORS INFLUENCING THE MAXIMUM RATES OF AIR DRYING SHELLED CORN IN THIN LAYERS. , 1949 .

[21]  M. M. Bertorello,et al.  In vitro sodium salicylate release from chitosan films , 1993 .

[22]  J. M. Bunn,et al.  Mechanical and barrier properties of edible chitosan films as affected by composition and storage , 1996 .

[23]  Y. Lee Modified chitosan membranes for pervaporation , 1993 .

[24]  P. Vergano,et al.  Chitosan Film Mechanical and Permeation Properties as Affected by Acid, Plasticizer, and Storage , 2006 .