Evidence for Multi-stage Magmatic Evolution during the past 60 kyr at Campi Flegrei (Italy) Deduced from Sr, Nd and Pb Isotope Data

The Campi Flegrei caldera, an active volcanic field in the Campanian INTRODUCTION province, Italy, is a nested structure generated by the Campanian At any stage of their ascent from source to surface, Ignimbrite (37 ka BP) and the Neapolitan Yellow Tuff (12 ka magmas may become contaminated by assimilation of BP) eruptions. Since at least 60 ka BP Campi Flegrei has produced wall rocks. In particular, crustal contamination is conmagmas with variable chemical and Sr isotopic compositions. Sr/ sidered a possible mechanism when mantle-derived Sr ratios increase through time from 0·7068 to 0·7086, with magmas rise through thick sections of continental crust the highest ratios detected in the least-evolved shoshonitic products. and pond at different depths before reaching the surface The origin of this progressive Sr isotopic variability has been (e.g. Leeman, 1983; Hawkesworth & van Calsteren, investigated using new Sr, Nd and Pb isotopic data for volcanic 1984). rocks and entrained xenoliths. The data obtained are combined and Crustal contamination of magmas is favoured in high discussed with previous geochemical and Sr isotope data and used heat flux zones and may occur in a variety of ways to suggest a multi-stage evolution for the magmatic system, mainly including: (1) bulk assimilation of crustal material; (2) involving deeper and shallower crustal magma storage reservoirs. assimilation of partial melts of crustal materials; (3) seThe deeper reservoir is proposed to be a magma chamber periodically lective exchange of specific elements (e.g. De Paolo, 1981; refilled by primitive mafic magmas which subsequently undergo Leeman, 1983; Huppert & Sparks, 1985; Wilson, 1989). contamination by crustal material. The assimilated crustal material Sr, Nd and Pb isotopes are commonly used to model is represented by xenoliths recovered in the shoshonitic pyroclastic crustal contamination processes (e.g. Wilson, 1989, and products. Magma batches originating from the deeper reservoir references therein). However, the nature of the conmigrated towards the surface and fed a shallower complex magmatic taminant is, in some cases, difficult to identify, in parsystem. The deeper chamber was tapped during the eruption of ticular when exposures of basement rocks or occurrences least evolved magmas by regional fault systems. In addition to of entrained xenoliths in the magmas are lacking. crystal–liquid fractionation, open-system processes occurred in the At Campi Flegrei (CF) (Fig. 1) magmas of different shallower system. chemical and Sr isotopic composition have been erupted since at least 60 ka BP (Civetta et al., 1991, 1997; Orsi

[1]  The Phlegraean Fields , 1897 .

[2]  R. W. Le Maitre,et al.  A Chemical Classification of Volcanic Rocks Based on the Total Alkali-Silica Diagram , 1986 .

[3]  I. Finetti,et al.  GEOPHYSICAL STUDY OF THE TYRRHENIAN OPENING , 1986 .

[4]  W. McDonough,et al.  Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes , 1989, Geological Society, London, Special Publications.

[5]  C. Hawkesworth,et al.  Radiogenic isotopes-some geological applications , 1984 .

[6]  P. Girolamo Geotectonic settings of miocene-quaternary volcanism in and around the eastern Tyrrhenian sea border (Italy) as deduced from major element geochemistry , 1978 .

[7]  L. Civetta,et al.  Timing of magma extraction during the Campanian Ignimbrite eruption (Campi Flegrei Caldera) , 2002 .

[8]  G. Pellis,et al.  Geothermal structure of the Tyrrhenian Sea , 1984 .

[9]  F. Innocenti,et al.  The phlegraean fields: Magma evolution within a shallow chamber , 1983 .

[10]  D. DePaolo Trace element and isotopic effects of combined wallrock assimilation and fractional crystallization , 1981 .

[11]  F. Innocenti,et al.  Geochemical and petrological evidence of the subduction of delaminated Adriatic continental lithosphere in the genesis of the Neogene-Quaternary magmatism of central Italy , 1993 .

[12]  B. Giannetti,et al.  The white trachytic tuff of Roccamonfina Volcano (Roman Region, Italy) , 1983 .

[13]  B. Giannetti Cumulate inclusions from K-rich magmas, Roccamonfina volcano, Italy , 1982 .

[14]  O. D. Hermes,et al.  Sr isotopic evidence for a multi-source origin of the potassic magmas in the neapolitan area (S. Italy) , 1981 .

[15]  L. Civetta,et al.  Chemical and Sr-isotopical evolution of the Phlegraean magmatic system before the Campanian Ignimbrite and the Neapolitan Yellow Tuff eruptions , 1999 .

[16]  A. Peccerillo,et al.  Relationships between intermediate and acidic rocks in orogenic granitoid suites: petrological, geochemical and isotopic (Sr, Nd, Pb) data from Capo Vaticano (southern Calabria, Italy) , 1991 .

[17]  P. Scandone,et al.  Structure and evolution of the Calabrian Arc , 1982 .

[18]  J. Virieux,et al.  P‐SV conversions at a shallow boundary beneath Campi Flegrei Caldera (Italy): Evidence for the magma chamber , 1992 .

[19]  Nobuo Morimoto,et al.  Nomenclature of Pyroxenes , 1988, Mineralogical Magazine.

[20]  R. Santacroce,et al.  The somma-vesuvius magma chamber: a petrological and volcanological approach , 1981 .

[21]  P. Holm,et al.  The geochemistry and petrogenesis of the lavas of the Vulsinian District, Roman province, Central Italy , 1982 .

[22]  I. Finetti,et al.  Geophysical Exploration of the Mediterranean Sea , 1973 .

[23]  L. Civetta,et al.  Step-filling and development of a three-layer magma chamber: the Neapolitan Yellow Tuff case history , 1995 .

[24]  Paul Henderson,et al.  Rare earth element geochemistry , 1984 .

[25]  M. A. Di Vito,et al.  The restless, resurgent Campi Flegrei nested caldera (Italy): constraints on its evolution and configuration , 1996 .

[26]  C. Hawkesworth,et al.  Crustal contamination versus enriched mantle: 143Nd/144Nd and 87Sr/86Sr evidence from the Italian volcanics , 1979 .

[27]  H. Huppert,et al.  Cooling and contamination of mafic and ultramafic magmas during ascent through continental crust , 1985 .

[28]  K. Wohletz,et al.  Thermal evolution of the Phlegraean magmatic system , 1999 .

[29]  B. Villemant Trace element evolution in the Phlegrean Fields (Central Italy): fractional crystallization and selective enrichment , 1988 .

[30]  L. Civetta,et al.  The present state of the magmatic system of the Campi Flegrei caldera based on a reconstruction of its behavior in the past 12 ka , 1999 .

[31]  H. Taylor,et al.  Oxygen isotope studies of potassic volcanic rocks of the Roman Province, Central Italy , 1976 .

[32]  A. Saunders,et al.  Magmatism in the Ocean Basins , 1989 .

[33]  G. Orsi,et al.  Magnetic modeling of the Phlegraean Volcanic District with extension to the Ponza archipelago, Italy , 1999 .

[34]  L. Civetta,et al.  Mantle source heterogeneity in the Campanian Region (South Italy) as inferred from geochemical and isotopic features of mafic volcanic rocks with shoshonitic affinity , 1999 .

[35]  Grant Heiken,et al.  Geochemical zoning, mingling, eruptive dynamics and depositional processes — the Campanian Ignimbrite, Campi Flegrei caldera, Italy , 1997 .

[36]  A. Peccerillo,et al.  Volcanological and petrological evolution of Vulcano island (Aeolian Arc, southern Tyrrhenian Sea) , 1997 .

[37]  P. Di Girolamo,et al.  Vulcanologia e petrologia dei Campi Flegrei , 1984 .

[38]  F. Aprile,et al.  Principali caratteristiche stratigrafiche e strutturali dei depositi superficiali della Piana Campana , 1985 .

[39]  R. Mazzuoli,et al.  The role of the crust in the magmatic evolution of the island of Lipari (Aeolian Islands, Italy) , 1992 .

[40]  F. Spera Energy-constrained open-system magmatic processes I : General model and energy-constrained assimilation and fractional crystallization (EC-AFC) formulation , 2001 .

[41]  J. D. Appleton Petrogenesis of Potassium-rich Lavas from the Roccamonfina Volcano, Roman Region, Italy , 1972 .