论文信息 - Indium-mediated coupling of aldehydes with prop-2-ynyl bromides in aqueous media - 字舞流文

Indium-mediated coupling of aldehydes with prop-2-ynyl bromides in aqueous media

Indium-mediated coupling of aldehydes 1 with prop-2-ynyl bromides 2 occurs regioseiectively to give either homoprop-2-ynyl alcohols 3 or allenylic alcohols 4 depending on the γ-substituent of the prop-2-ynyl bromide.

T. Chan | M. Isaac

[1] R. Friesen,et al. Total synthesis of (±)-9-deoxygoniopypyrone , 1994 .

[2] Chao-Jun Li,et al. 1993 R.U. Lemieux Award Lecture Organometallic-type reactions in aqueous media—a new challenge in organic synthesis , 1994 .

[3] Chao-Jun Li. Organic reactions in aqueous media - with a focus on carbon-carbon bond formation , 1993 .

[4] G. Whitesides,et al. Tin- and indium-mediated allylation in aqueous media : application to unprotected carbohydrates , 1993 .

[5] Chao-Jun Li,et al. Organometallic reactions in aqueous media. 2. Convenient synthesis of methylenetetrahydrofurans , 1991 .

[6] M. Guazzaroni,et al. Synthesis of homoallylic alcohols in aqueous media , 1989 .

[7] J. Luche,et al. Selective tin and zinc mediated allylations of carbonyl compounds in aqueous media , 1985 .