High-resolution stress assessments of interconnect/dielectric electronic patterns using optically active point defects of silica glass as a stress sensor

A piezospectroscopic (PS) cathodoluminescence (CL) study has been carried out on a Cu-Ta∕SiOx (carbon-doped) model chip prepared on a Si substrate. The PS approach was applied to CL spectra arising from optically active point defects in dielectric silica. The red CL emission arising from nonbridging oxygen hole centers (NBOHC) in the carbon-doped SiOx dielectric layer was calibrated and used as a stress sensor. This approach enabled us to locate the trace of the residual stress tensor, as locally developed during manufacturing process in the dielectric interlayers between Cu-Ta interconnects. A minimally invasive electron beam allowed probing local residual stress fields with an improved spatial resolution as compared to more conventional photostimulated PS techniques applied to the Si substrate. In addition, a two-dimensional deconvolution procedure was attempted to retrieve the “true” residual stress distribution piled up between adjacent Cu-Ta lines, according to a theoretical model for embedded struct...

[1]  Saulius Juodkazis,et al.  Luminescence and defect formation by visible and near-infrared irradiation of vitreous silica , 1999 .

[2]  J. Rödel,et al.  Crack Opening Profiles of Indentation Cracks in Normal and Anomalous Glasses , 2004 .

[3]  I. Wolf Micro-Raman spectroscopy to study local mechanical stress in silicon integrated circuits , 1996 .

[4]  S. Okayama,et al.  Penetration and energy-loss theory of electrons in solid targets , 1972 .

[5]  Shu-Sheng Chiang,et al.  THE RESPONSE OF SOLIDS TO ELASTIC/ PLASTIC INDENTATION , 1980 .

[6]  Analytic solution of stress distribution under a thin film edge in substrates , 2001 .

[7]  Photoelastic study of stress field under thin oxide film edge in silicon and the validity of the concentrated force model , 2002 .

[8]  Y. Hama,et al.  2.7-eV luminescence in as-manufactured high-purity silica glass. , 1989, Physical review letters.

[9]  I. De Wolf,et al.  Stresses and strains in lattice‐mismatched stripes, quantum wires, quantum dots, and substrates in Si technology , 1996 .

[10]  Linards Skuja,et al.  The origin of the intrinsic 1.9 eV luminescence band in glassy SiO2 , 1994 .

[11]  Z. Suo,et al.  8.08 – Reliability of Metal Interconnects , 2003 .

[12]  D. Clarke,et al.  Piezospectroscopic Determination of Residual Stresses in Polycrystalline Alumina , 1994 .

[13]  E. Yoffe,et al.  Elastic stress fields caused by indenting brittle materials , 1982 .

[14]  A. Szekeres,et al.  Study of thin SiO2 and its interface formed by thermal oxidation of rf hydrogen plasma-cleaned silicon , 2001 .

[15]  D. Griscom E ′ center in glassy Si O 2 : O 17 , H 1 , and "very weak" Si 29 superhyperfine structure , 1980 .

[16]  T. Fett Computation of the crack opening displacements for Vickers indentation cracks , 2002 .

[17]  Ludwig Grabner,et al.  Spectroscopic technique for the measurement of residual stress in sintered Al2O3 , 1978 .

[18]  C. Donolato An analytical model of SEM and STEM charge collection images of dislocations in thin semiconductor layers: I. Minority carrier generation, diffusion, and collection , 1981 .

[19]  T. Belmonte,et al.  Detection by emission spectroscopy of active species in plasma–surface processes , 1999 .

[20]  K. Matsuda,et al.  Characterization of silicon dioxide film by high spatial resolution cathodoluminescence spectroscopy , 2002 .

[21]  L. Skuja,et al.  A new intrinsic defect in amorphous SiO2: Twofold coordinated silicon , 1984 .

[22]  Magnus Willander,et al.  A method to interpret micro-Raman experiments made to measure nonuniform stresses: Application to local oxidation of silicon structures , 1998 .

[23]  J. Rödel,et al.  In Situ Measurements of Bridged Crack Interfaces in the Scanning Electron Microscope , 1990 .

[24]  David R. Clarke,et al.  Polarization Dependence of the Cr3+ R‐Line Fluorescence from Sapphire and Its Application to Crystal Orientation and Piezospectroscopic Measurement , 1997 .

[25]  J. Rödel,et al.  Measurement of Crack Tip Toughness in Alumina as a Function of Grain Size , 2005 .

[26]  J. R. Zhang,et al.  PHOTOLUMINESCENCE STUDY OF DEFECTS IN SI+ ION IMPLANTED THERMAL SIO2 FILMS , 1998 .

[27]  Ohki,et al.  Correlation of the 5.0- and 7.6-eV absorption bands in SiO2 with oxygen vacancy. , 1989, Physical review. B, Condensed matter.

[28]  B. Leroy Stresses and silicon interstitials during the oxidation of a silicon substrate , 1987 .

[29]  Hiroshi Tada,et al.  The stress analysis of cracks handbook , 2000 .

[30]  Hiroshi Koyama,et al.  Cathodoluminescence study of SiO2 , 1980 .

[31]  S. M. Xiaolei Hu,et al.  Film-Edge-Induced Stress in Silicon Substrates , 1978 .

[32]  P. Venturi,et al.  Influence of the Generation Distribution on the Calculated EBIC Contrast of Line Defects , 1982, October 16.

[33]  David R. Clarke,et al.  Dielectric cracking produced by electromigration in microelectronic interconnects , 2000 .

[34]  L. Skuja Optically active oxygen-deficiency-related centers in amorphous silicon dioxide , 1998 .

[35]  B. Schmidt,et al.  Multiplet luminescence of sulfur implanted silica – SiO2:S , 2005 .

[36]  G. Pezzotti,et al.  Electron probe response function and piezo-spectroscopic behaviour of semiconductor materials in presence of highly graded stress fields , 2006 .

[37]  S. M. Hu,et al.  Stress‐related problems in silicon technology , 1991 .

[38]  H. Fitting,et al.  Electron penetration and energy transfer in solid targets , 1977 .

[39]  William H. Press,et al.  Numerical recipes in C , 2002 .

[40]  J. Rice,et al.  Elementary engineering fracture mechanics , 1974 .

[41]  Zhigang Suo,et al.  High‐resolution determination of the stress in individual interconnect lines and the variation due to electromigration , 1995 .

[42]  Anatoly N. Trukhin,et al.  Cathodoluminescence of crystalline and amorphous SiO2 and GeO2 , 2001 .

[43]  G. Pezzotti,et al.  Stress dependence of the cathodoluminescence spectrum of N-doped 3C‐SiC , 2006 .

[44]  Fred H. Pollak,et al.  Effect of static uniaxial stress on the Raman spectrum of silicon , 1993 .

[45]  M. Pagel,et al.  Cathodoluminescence of quartz from sandstones: Interpretation of the UV range by determination of trace element distributions and fluid-inclusion P-T-X properties in authigenic quartz , 1996 .