Fast electro-optical effect in polymer-stabilized blue phases

Key challenges in achieving higher-quality liquid crystal displays for future generations are developing new liquid crystal materials with faster electro-optical response and simplifying the fabrication process of devices. Blue phases1-4, kinds of liquid crystal phases, have two major advantages over commonly used nematic phases. First, the response is much faster5-8. Second, the zero-electric field state is optically isotropic unlike nematic phases, that is, no surface treatment (no rubbing) is necessary, leading to a simplification of the fabrication process. One of the problems of blue phases that the available temperature range is very narrow has been overcome by our recent achievement, the polymer-stabilized blue phases9,10. Here we show that the polymer-stabilized blue phases surmount another problem that the blue phase is very fragile to an electric field. We also demonstrate the sufficiently large electric field-induced birefringence and the micro-second response of the polymer-stabilized blue phases without any surface treatment.

[1]  Paul R. Gerber,et al.  Electro-Optical Effects of a Small-Pitch Blue-Phase System , 1985 .

[2]  D. Johnson,et al.  Structure and Properties of the Cholesteric Blue Phases , 1980 .

[3]  M. Krumrey,et al.  Observation of Electro-Optical Effects in Blue Phase Systems , 1983 .

[4]  Masayuki Yokota,et al.  Polymer-stabilized liquid crystal blue phases , 2002, Nature materials.

[5]  James P. Sethna,et al.  Theory of the blue phase of cholesteric liquid crystals. , 1981 .

[6]  N. David Mermin,et al.  Crystalline liquids: the blue phases , 1989 .

[7]  F. Porsch,et al.  Electric field effect on phase transitions in liquid-crystalline blue-phase systems , 1984 .

[8]  H. Coles,et al.  Dynamic properties of blue-phase mixtures , 1989 .

[9]  H. Kitzerow,et al.  Electrostriction of the cholesteric blue phases BPI and BPII in mixtures with positive dielectric anisotropy , 1989 .

[10]  F. Porsch,et al.  The effect of an electric field on the selective reflection bands of liquid crystalline blue phases , 1986 .

[11]  Horst Stegemeyer,et al.  Thermodynamic, structural and morphological studies on liquid-crystalline blue phases , 1986 .

[12]  Friedrich Reinitzer,et al.  Beiträge zur Kenntniss des Cholesterins , 1888 .

[13]  I. Dierking The Blue Phases , 2004 .

[14]  H. Coles,et al.  Electric Field Induced Phase Transitions and Colour Switching in the Blue Phases of Chiral Nematic Liquid Crystals , 1989 .

[15]  Gerd Heppke,et al.  Electrostriction of BPI and BPII for blue phase systems with negative dielectric anisotropy , 1989 .