Taming the beast: fluoromesityl groups induce a dramatic stability enhancement in boroles
暂无分享,去创建一个
Holger Braunschweig | Todd B. Marder | Martin Haehnel | Michael Meier | Zuolun Zhang | Robert M. Edkins | Marius Wehner | Antonius Eichhorn | Lisa Mailänder | Johannes Brand | Franziska Brede | Klaus Müller-Buschbaum | K. Müller‐Buschbaum | H. Braunschweig | Zuolun Zhang | F. Brede | Martin Haehnel | A. Eichhorn | Johannes Brand | Lisa Mailänder | M. Meier | T. Marder | Marius Wehner
[1] Khai Leok Chan,et al. Organic non-fullerene acceptors for organic photovoltaics , 2011 .
[2] K. Tamao,et al. Dibenzoborole-Containing π-Electron Systems: Remarkable Fluorescence Change Based on the “On/Off” Control of the pπ−π* Conjugation , 2002 .
[3] T. Kupfer,et al. Direct functionalization at the boron center of antiaromatic chloroborole. , 2008, Chemical communications.
[4] M. Yamashita. Nucleophilicity of a base-stabilized borole anion at the boron center. , 2010, Angewandte Chemie.
[5] Hiroshi Kageyama,et al. Charge carrier transporting molecular materials and their applications in devices. , 2007, Chemical reviews.
[6] TakahashiTamotsu,et al. A Convenient Preparative Method of Dibromoterphenyl and Bis(bromophenyl)diene Monomers Using Zirconacyclopentadienes , 1999 .
[7] T. Kupfer,et al. Structural evidence for antiaromaticity in free boroles. , 2008, Angewandte Chemie.
[8] A. Rheingold,et al. Bora-aromatic systems. 12. Thermal generation and transformation of the borepin ring system: a paradigm of pericyclic processes , 1990 .
[9] Christopher D. Entwistle,et al. Synthesis and characterisation of some new boron compounds containing the 2,4,6-(CF3)3C6H2(fluoromes = Ar), 2,6-(CF3)2C6H3(fluoroxyl = Ar′), or 2,4-(CF3)2C6H3(Ar″) ligands , 2003 .
[10] T. Kupfer,et al. Recent developments in the chemistry of antiaromatic boroles. , 2011, Chemical communications.
[11] T. Kupfer,et al. The pentaphenylborole-2,6-lutidine adduct: a system with unusual thermochromic and photochromic properties. , 2011, Angewandte Chemie.
[12] H. Braunschweig,et al. An isolable radical anion based on the borole framework. , 2012, Angewandte Chemie.
[13] K. Nozaki. Chemistry: Not just any old anion , 2010, Nature.
[14] T. Kupfer,et al. Chemical reduction and dimerization of 1-chloro-2,3,4,5-tetraphenylborole. , 2010, Chemistry.
[15] J. Ko,et al. The role of borole in a fully conjugated electron-rich system. , 2004, Chemical communications.
[16] Preston A. Chase,et al. New Fluorinated 9-Borafluorene Lewis Acids , 2000 .
[17] Robert M. Edkins,et al. D-π-A triarylboron compounds with tunable push-pull character achieved by modification of both the donor and acceptor moieties. , 2015, Chemistry.
[18] W. Piers,et al. Photochemical synthesis of a ladder diborole: a new boron-containing conjugate material. , 2012, Angewandte Chemie.
[19] F. Jäkle. Advances in the synthesis of organoborane polymers for optical, electronic, and sensory applications. , 2010, Chemical reviews.
[20] M. Wagner,et al. Confirmed by X-ray crystallography: the B⋅B one-electron σ bond. , 2014, Angewandte Chemie.
[21] T. B. Marder,et al. Applications of Three-Coordinate Organoboron Compounds and Polymers in Optoelectronics , 2004 .
[22] B. Wrackmeyer,et al. Organoborierung von alkinylstannanen: XVI. borol-synthese über die organoborierung von BIS(alknyl)Boranen , 1986 .
[23] H. Braunschweig,et al. Platinum substituted boroles. , 2010, Chemical communications.
[24] A. Wakamiya,et al. Synthesis and Structural Characterization of Pentaarylboroles and Their Dianions , 2008 .
[25] T. Kupfer,et al. Synthesis, structure, and reactivity of borole-functionalized ferrocenes. , 2012, Chemistry.
[26] Christopher D. Entwistle,et al. Boron chemistry lights the way: optical properties of molecular and polymeric systems. , 2002, Angewandte Chemie.
[27] Rian D. Dewhurst,et al. Evidence for extensive single-electron-transfer chemistry in boryl anions: isolation and reactivity of a neutral borole radical. , 2014, Angewandte Chemie.
[28] Dominik Nied,et al. The reduction chemistry of ferrocenylborole. , 2010, Angewandte Chemie.
[29] W. Piers,et al. Mechanistic studies on the metal-free activation of dihydrogen by antiaromatic pentarylboroles. , 2013, Journal of the American Chemical Society.
[30] R. Lalancette,et al. Highly electron-deficient and air-stable conjugated thienylboranes. , 2014, Angewandte Chemie.
[31] Joan Vignolle,et al. Perfluoropentaphenylborole: a new approach to Lewis acidic, electron-deficient compounds. , 2009, Angewandte Chemie.
[32] R. Boese,et al. Borole Dianions: Metalation of 1‐(Dialkylamino)‐2,5‐dihydro‐lH‐boroles and the Structure of Li2 (C4 H4 BNEt2)·TMEDA , 1990 .
[33] G. Erker,et al. Reactions of Boroles Formed by 1,1-Carboboration , 2015 .
[34] S. Yamaguchi,et al. Thiophene-fused ladder boroles with high antiaromaticity. , 2011, Journal of the American Chemical Society.
[35] S. Yamaguchi,et al. Electron-donating tetrathienyl-substituted borole. , 2012, Angewandte Chemie.
[36] J. Eisch,et al. Synthesis of pentaphenylborole, a potentially antiaromatic system , 1969 .
[37] T. Kupfer,et al. 1-Heteroaromatic-substituted tetraphenylboroles: π-π interactions between aromatic and antiaromatic rings through a B-C bond. , 2012, Journal of the American Chemical Society.
[38] T. Kupfer,et al. Synthesis, coordination behavior, and reduction chemistry of cymantrenyl-1,3-bis(2,3,4,5-tetraphenyl)borole. , 2012, Chemistry.
[39] F. Leroux. Atropisomerism, Biphenyls, and Fluorine: A Comparison of Rotational Barriers and Twist Angles , 2004, Chembiochem : a European journal of chemical biology.
[40] G. Erker,et al. Borole formation by 1,1-carboboration. , 2014, Journal of the American Chemical Society.
[41] J. E. Galle,et al. Rearrangements of organometallic compounds. XIII. Boraaromatic systems. IV. Synthesis of heptaphenylborepin via the thermal rearrangement of heptaphenyl-7-borabicyclo[2.2.1]heptadiene , 1975 .
[42] P. Fagan,et al. Synthesis of boroles and their use in low-temperature Diels−Alder reactions with unactivated alkenes , 1988 .
[43] H. Braunschweig,et al. Antiaromaticity to aromaticity: from boroles to 1,2-azaborinines by ring expansion with azides. , 2014, Chemistry.
[44] H. Braunschweig,et al. Free Boroles: The Effect of Antiaromaticity on Their Physical Properties and Chemical Reactivity , 2013 .
[45] G. Molander,et al. Scope of the palladium-catalyzed aryl borylation utilizing bis-boronic acid. , 2012, Journal of the American Chemical Society.
[46] Rosendo Valero,et al. Consistent van der Waals radii for the whole main group. , 2009, The journal of physical chemistry. A.
[47] J. E. Galle,et al. Bora-aromatic systems. Part 8. The physical and chemical consequences of cyclic conjugation in boracyclopolyenes. The antiaromatic character of pentaarylboroles. , 1986, Journal of the American Chemical Society.
[48] R. McDonald,et al. Divergent Reactivity of Perfluoropentaphenylborole with Alkynes , 2010 .
[49] Suning Wang,et al. Enhancing electron accepting ability of triarylboron via pi-conjugation with 2,2'-bipy and metal chelation: 5,5'-bis(BMes(2))-2,2'-bipy and its metal complexes. , 2007, Journal of the American Chemical Society.
[50] Andreas Steffen,et al. Dibenzometallacyclopentadienes, boroles and selected transition metal and main group heterocyclopentadienes: Synthesis, catalytic and optical properties , 2010 .
[51] Q. Peng,et al. Synthesis and properties of B,N-bridged p-terphenyls. , 2014, Chemical communications.
[52] W. Piers,et al. Reaction of pentaarylboroles with carbon monoxide: an isolable organoboron carbonyl complex , 2012 .
[53] B. Wrackmeyer,et al. Organoborierung von alkinylstannanen : IV. Zur darstellung verschiedenartig substituierter 1-stannacyclopentadiene , 1978 .
[54] A. Wakamiya,et al. Kinetically stabilized dibenzoborole as an electron-accepting building unit. , 2008, Chemical communications.
[55] T. Kupfer,et al. Oligo(borolyl)benzenes--synthesis and properties. , 2012, Chemistry.
[56] M. Wagner,et al. Main-chain boron-containing oligophenylenes via ring-opening polymerization of 9-H-9-borafluorene. , 2011, Journal of the American Chemical Society.
[57] W. Oschmann,et al. Two Routes to Complex Derivatives of Borole , 1977 .
[58] M. Wagner,et al. A preorganized ditopic borane as highly efficient one- or two-electron trap. , 2015, Journal of the American Chemical Society.
[59] T. Kupfer,et al. Synthesis and structure of a carbene-stabilized pi-boryl anion. , 2010, Angewandte Chemie.