Open-source predictive simulators for scale-up of direct contact membrane distillation modules for seawater desalination

Abstract Proper industrial-scale module design for seawater desalination by means of direct contact membrane distillation (DCMD) can be aided by module simulation. Accordingly, two open-source simulators (of flat sheet membranes and hollow fibre membranes) were developed on the Matlab GUI platform to supplement DCMD module scale-up. A coupled “tanks-in-series” and “black box” mathematical approach was developed not only to yield accurate simulation, but also to produce profiles of all the key parameters versus membrane length. Using laboratory-scale experimental results in one configuration as simulation inputs, the developed simulators were able to predict large-scale DCMD module performance in both co-current and counter-current configurations. These predictions exhibited good accuracy in both laboratory-scale and large-scale. Design considerations informing appropriate module scale-up for the DCMD process were demonstrated using the simulators. Key design criteria for industrial-scale module design were identified and evaluated. The results presented in this study offer general and practical guidance for proper module scale-up to deliver optimal pure water productivity for industrial-scale seawater desalination using the DCMD process. More importantly, the developed simulators are open-source, available for all researchers to develop specific DCMD module scale-up strategies for their own membranes.

[1]  John H. Lienhard,et al.  Energy efficiency comparison of single-stage membrane distillation (MD) desalination cycles in different configurations , 2012 .

[2]  Mohamed A. Antar,et al.  Experimental and theoretical investigation on water desalination using air gap membrane distillation , 2015 .

[3]  Mohamed Khayet,et al.  Numerical simulation and experimental studies on heat and mass transfer using sweeping gas membrane distillation , 2010 .

[4]  Linh T. T. Vu,et al.  Modelling the simultaneous heat and mass transfer of direct contact membrane distillation in hollow fibre modules , 2010 .

[5]  D. R. Lloyd,et al.  Membrane distillation. II. Direct contact MD , 1996 .

[6]  Enrico Drioli,et al.  Direct contact membrane distillation: modelling and concentration experiments , 2000 .

[7]  Enrico Drioli,et al.  Experimental and theoretical evaluation of temperature polarization phenomenon in direct contact membrane distillation , 2013 .

[8]  Anthony G. Fane,et al.  Heat and mass transfer in membrane distillation , 1987 .

[9]  Hyo-Taek Chon,et al.  Structural analysis and modeling of the commercial high performance composite flat sheet membranes for membrane distillation application , 2014 .

[10]  Jack Gilron,et al.  Design for Cascade of Crossflow Direct Contact Membrane Distillation , 2007 .

[11]  Frank J. Millero,et al.  Heat capacity of seawater solutions from 5° to 35°C and 0.5 to 22‰ chlorinity , 1973 .

[12]  E. N. Sieder,et al.  Heat Transfer and Pressure Drop of Liquids in Tubes , 1936 .

[13]  Menachem Elimelech,et al.  Direct contact membrane distillation with heat recovery: Thermodynamic insights from module scale modeling , 2014 .

[14]  Mohamed Khayet,et al.  A framework for better understanding membrane distillation separation process , 2006 .

[15]  Chris Dotremont,et al.  Characterization and performance evaluation of commercially available hydrophobic membranes for direct contact membrane distillation , 2016 .

[16]  Xing Yang,et al.  Numerical simulation of heat and mass transfer in direct membrane distillation in a hollow fiber module with laminar flow , 2011 .

[17]  Ratana Jiraratananon,et al.  Direct contact membrane distillation: effect of mass transfer on heat transfer , 2001 .

[18]  Baoli Shi,et al.  Preparation and properties of microporous membrane from poly(vinylidene fluoride-co-tetrafluoroethylene) (F2.4) for membrane distillation , 2004 .

[19]  Anthony G. Fane,et al.  Gas and vapour transport through microporous membranes. I. Knudsen-Poiseuille transition , 1990 .

[20]  J. Lienhard,et al.  Erratum to Thermophysical properties of seawater: A review of existing correlations and data , 2010 .

[21]  Ingmar Nopens,et al.  Influence of membrane thickness and process conditions on direct contact membrane distillation at different salinities , 2016 .

[22]  Robert W. Field,et al.  Direct contact membrane distillation: An experimental and analytical investigation of the effect of membrane thickness upon transmembrane flux , 2014 .

[23]  Enrico Drioli,et al.  Membrane distillation: Recent developments and perspectives , 2015 .

[24]  Kyung Taek Woo,et al.  Simulation and feasibility study of using thermally rearranged polymeric hollow fiber membranes for various industrial gas separation applications , 2015 .

[25]  Anthony G. Fane,et al.  Direct contact membrane distillation mechanism for high concentration NaCl solutions , 2006 .

[26]  E. Drioli,et al.  Thermally rearranged polymer membranes for desalination , 2016 .

[27]  Ho Jung Hwang,et al.  Production of drinking water from saline water by direct contact membrane distillation (DCMD) , 2011 .

[28]  Takeshi Matsuura,et al.  Simulation of heat and mass transfer in direct contact membrane distillation (MD): The effect of membrane physical properties , 2005 .

[29]  M. Qtaishat,et al.  Heat and mass transfer analysis in direct contact membrane distillation , 2008 .

[30]  L. Martinez-diez,et al.  A method to evaluate coefficients affecting flux in membrane distillation , 2000 .

[31]  Stephen R Gray,et al.  Direct contact membrane distillation (DCMD): Experimental study on the commercial PTFE membrane and , 2011 .

[32]  Guangzhi Zuo,et al.  Energy efficiency evaluation and economic analyses of direct contact membrane distillation system using Aspen Plus , 2011 .

[33]  Don W. Green,et al.  Perry's Chemical Engineers' Handbook , 2007 .

[34]  E. Drioli,et al.  Membrane Distillation and Related Operations—A Review , 2005 .

[35]  Ho-Ming Yeh,et al.  Theoretical modeling and experimental analysis of direct contact membrane distillation , 2009 .

[36]  Jack Gilron,et al.  Direct Contact Membrane Distillation-Based Desalination: Novel Membranes, Devices, Larger-Scale Studies, and a Model , 2007 .

[37]  Anthony G. Fane,et al.  Heat transport and membrane distillation coefficients in direct contact membrane distillation , 2003 .

[38]  Xing Yang,et al.  Performance improvement of PVDF hollow fiber-based membrane distillation process , 2011 .

[39]  Andrew G. Livingston,et al.  Increasing the sustainability of membrane processes through cascade approach and solvent recovery—pharmaceutical purification case study , 2014 .

[40]  M. Khayet Membranes and theoretical modeling of membrane distillation: a review. , 2011, Advances in colloid and interface science.

[41]  Meisam Tabatabaei,et al.  Evaluation of commercial PTFE membranes in desalination by direct contact membrane distillation , 2014 .

[42]  Benny D. Freeman,et al.  Modeling multicomponent gas separation using hollow‐fiber membrane contactors , 1998 .

[43]  Frank J. Millero,et al.  International one-atmosphere equation of state of seawater , 1981 .

[44]  Anthony G. Fane,et al.  Mass transfer mechanisms and transport resistances in direct contact membrane distillation process , 2006 .

[45]  E. Drioli,et al.  Potential of membrane distillation in seawater desalination: Thermal efficiency, sensitivity study and cost estimation , 2008 .

[46]  B. M. Fabuss,et al.  Viscosities of aqueous solutions of several electrolytes present in sea water , 1969 .

[47]  Marek Gryta,et al.  Heat transport in the membrane distillation process , 1998 .

[48]  Robert E. Wilson,et al.  Fundamentals of momentum, heat, and mass transfer , 1969 .

[49]  L. Martinez-diez,et al.  Temperature and concentration polarization in membrane distillation of aqueous salt solutions , 1999 .