Removal and determination of trimethylsilanol from the landfill gas.

The removal and determination of trimethylsilanol (TMSOH) in landfill gas has been studied before and after the special E3000-ITC System. The system works according to principle of temperature swing. The performance of TMSOH and humidity removal was 20% and more than 90%, respectively. The six of active carbons and impinger method were tested on the full-scale landfill in Poland for TMSOH and siloxanes determination. The extraction method and absorption in acetone were used. The concentration of TMSOH and siloxanes were found in range from 23.6 to 29.2 mg/m3 and from 18.0 to 38.9 mg/m3, respectively. The content of TMSOH in biogas originating from landfill was 41% out of all siloxanes. Moreover, the used system is alternative to other existing technique of landfill gas purification.

[1]  H. Schröder,et al.  Cyclic siloxanes in the biological waste water treatment process – Determination, quantification and possibilities of elimination , 1996 .

[2]  M. Arnold,et al.  Development of on-line measurement techniques for siloxanes and other trace compounds in biogas. , 2010, Waste management.

[3]  T. Melin,et al.  Siloxane removal from landfill and digester gas - a technology overview. , 2010, Bioresource technology.

[4]  J. Baeyens,et al.  Principles and potential of the anaerobic digestion of waste-activated sludge , 2008 .

[5]  W. Urban,et al.  Catalytically upgraded landfill gas as a cost-effective alternative for fuel cells , 2009 .

[6]  R. Niessner,et al.  Removal of siloxanes in biogases. , 2001, Journal of hazardous materials.

[7]  P. Le Cloirec,et al.  Biogas pre-upgrading by adsorption of trace compounds onto granular activated carbons and an activated carbon fiber-cloth. , 2009, Water science and technology : a journal of the International Association on Water Pollution Research.

[8]  P. Hentschel,et al.  Determination of siloxanes in biogas from landfills and sewage treatment plants , 2002 .

[9]  R. Niessner,et al.  Determination of Siloxanes and VOC in Landfill Gas and Sewage Gas by Canister Sampling and GC-MS/AES Analysis , 1999 .

[10]  P. Germain,et al.  Volatile organic silicon compounds: the most undesirable contaminants in biogases. , 2008, Water science and technology : a journal of the International Association on Water Pollution Research.

[11]  A. Hirner,et al.  Determination of trimethylsilanol in the environment by LT-GC/ICP-OES and GC-MS , 1998 .

[12]  S. Dorn,et al.  Study of the degradation of polydimethylsiloxanes on soil. , 1995, Environmental science & technology.

[13]  Jeremy Williams Landfill Gas to Fuel , 2008 .

[14]  A. Hirner,et al.  HPLC/ICP-OES determination of water-soluble silicone (PDMS) degradation products in leachates , 1999 .

[15]  T. Melin,et al.  Suitability of Tedlar gas sampling bags for siloxane quantification in landfill gas. , 2010, Talanta.

[16]  A. Narros,et al.  DETERMINATION OF SILOXANES IN LANDFILL GAS BY ADSORPTION ON TENAX TUBES AND TD-GC-MS , 2009 .

[17]  Georg M. Guebitz,et al.  Siloxane removal from biogas by biofiltration: biodegradation studies , 2008 .

[18]  T. Matsui,et al.  Removal of siloxane from digestion gas of sewage sludge. , 2010, Bioresource technology.

[19]  R. G. Lehmann,et al.  Degradation of silicone polymer in a variety of soils , 1995 .

[20]  J. Rintala,et al.  Determination of organic silicon compounds in biogas from wastewater treatments plants, landfills, and co-digestion plants , 2010 .

[21]  Raf Dewil,et al.  The analysis of volatile siloxanes in waste activated sludge. , 2007, Talanta.