Design of Solution-Grown ZnO Nanostructures

The renewed interest of the scientific community in zinc oxide (ZnO) during the last decade has been mostly powered by the development of new low-temperature methods for the synthesis of ZnO nanostructures with a controlled morphology. The wide variety of morphology includes nanoparticles, nanowires, nanorods, nanotubes, nanosheets, as well as nanoporous films. The present chapter is a review of the most recent progresses made in the design of these structures by the use of different solution-based low-temperature preparation methods. The methods include chemical, sol-gel and hydrothermal synthesis, electrospinning, electroless deposition and electrodeposition. Special attention is paid to the preparation of organic/inorganic hybrid films, to patterning and to the doping of nanostructured ZnO layers. The interest in these nanostructures is illustrated by a large variety of applications, such as in solar cells, light emitting diodes (LED), photocatalysis and surfaces with controllable wettability.

[1]  Synthesis and optical properties of ZnO multipod nanorods , 2007 .

[2]  Takashi Sekiguchi,et al.  Low‐Temperature Fabrication of Light‐Emitting Zinc Oxide Micropatterns Using Self‐Assembled Monolayers , 2002 .

[3]  M. Izaki,et al.  Electrolyte Optimization for Cathodic Growth of Zinc Oxide Films , 1996 .

[4]  S. Xie,et al.  ZnO flowers made up of thin nanosheets and their optical properties , 2005 .

[5]  Marc A. Anderson,et al.  Semiconductor clusters in the sol-gel process: quantized aggregation, gelation, and crystal growth in concentrated zinc oxide colloids , 1991 .

[6]  Sten-Eric Lindquist,et al.  Three-dimensional array of highly oriented crystalline ZnO microtubes , 2001 .

[7]  Bixia Lin,et al.  Green luminescent center in undoped zinc oxide films deposited on silicon substrates , 2001 .

[8]  Xintang Huang,et al.  PEG-assisted synthesis of ZnO nanotubes , 2006 .

[9]  Bruce E. Gnade,et al.  Mechanisms behind green photoluminescence in ZnO phosphor powders , 1996 .

[10]  S. Watase,et al.  Low‐Temperature Electrodeposition of Room‐Temperature Ultraviolet‐Light‐Emitting Zinc Oxide , 2003 .

[11]  Daniel T. Schwartz,et al.  Electrodeposited Nanocomposite n–p Heterojunctions for Solid-State Dye-Sensitized Photovoltaics , 2000 .

[12]  Takafumi Yao,et al.  Plasma assisted molecular beam epitaxy of ZnO on c -plane sapphire: Growth and characterization , 1998 .

[13]  D. Lincot,et al.  Electrochemical growth of epitaxial eosin/ZnO hybrid films , 2003 .

[14]  Hiroaki Imai,et al.  Growth conditions for wurtzite zinc oxide films in aqueous solutions , 2002 .

[15]  Michael G. Spencer,et al.  Heteroepitaxy of ZnO on GaN and its implications for fabrication of hybrid optoelectronic devices , 1998 .

[16]  U. Pal,et al.  Controlling the morphology of ZnO nanostructures in a low-temperature hydrothermal process. , 2005, The journal of physical chemistry. B.

[17]  Yiying Wu,et al.  Room-Temperature Ultraviolet Nanowire Nanolasers , 2001, Science.

[18]  D. Lincot,et al.  Deposition of mixed zinc oxide/lanthanide films by electrochemical precipitation: The ZnO/Er system , 2006 .

[19]  Michael Grätzel,et al.  Electrochemical Deposition of Smooth and Homogeneously Mesoporous ZnO Films from Propylene Carbonate Electrolytes , 2001 .

[20]  Bruno Viana,et al.  Luminescence of Nanostructured Eu3+/ZnO Mixed Films Prepared by Electrodeposition , 2007 .

[21]  Michael H. Huang,et al.  Hydrothermal synthesis of ZnO microspheres and hexagonal microrods with sheetlike and platelike nanostructures. , 2005, The journal of physical chemistry. B.

[22]  M. Jafelicci,et al.  Luminescent properties and lattice defects correlation on zinc oxide , 2001 .

[23]  Lanthanide ion probes of structure in biology. Laser-induced luminescence decay constants provide a direct measure of the number of metal-coordinated water molecules , 1979 .

[24]  E. Samulski,et al.  Synthesis of variable-aspect-ratio, single-crystalline ZnO nanostructures. , 2006, Inorganic chemistry.

[25]  Faqiang Xu,et al.  The electronic structure and spectral properties of ZnO and its defects , 2003 .

[26]  Margaret A. K. Ryan,et al.  Fabrication and characterization of ZnO nanowires/CdSe/CuSCN eta-solar cell , 2006 .

[27]  D. Lincot,et al.  Cathodic Electrodeposition of ZnO/Eosin Y Hybrid Thin Films from Oxygen-Saturated Aqueous Solution of ZnCl2 and Eosin Y , 2003 .

[28]  K. Yoshino,et al.  Photoluminescence studies of high-quality ZnO single crystals by hydrothermal method , 2006 .

[29]  Eric A. Meulenkamp,et al.  Synthesis and Growth of ZnO Nanoparticles , 1998 .

[30]  T. Pauporté Highly Transparent ZnO/Polyvinyl Alcohol Hybrid Films with Controlled Crystallographic Orientation Growth , 2007 .

[31]  Lisha Zhang,et al.  Electrodeposited nanoporous ZnO films exhibiting enhanced performance in dye-sensitized solar cells , 2006 .

[32]  W. Cai,et al.  Different ZnO Nanostructures Fabricated by a Seed-Layer Assisted Electrochemical Route and Their Photoluminescence and Field Emission Properties , 2007 .

[33]  W. Horrocks,et al.  Lanthanide ion probes of structure in biology. Environmentally sensitive fine structure in laser-induced terbium(III) luminescence. , 1979, Biochimica et biophysica acta.

[34]  Daniel Lincot,et al.  Electrochemical deposition of zinc oxide films from non-aqueous solution: a new buffer/window process for thin film solar cells , 2000 .

[35]  Daniel Lincot,et al.  Heteroepitaxial electrodeposition of zinc oxide films on gallium nitride , 1999 .

[36]  C. Lévy-Clément,et al.  Electrodeposition of arrays of ZnO nanostructures and application to photoelectrochemical devices , 2006, SPIE Optics + Photonics.

[37]  P. O’Brien,et al.  Novel low temperature solution deposition of perpendicularly orientated rods of ZnO: substrate effects and evidence of the importance of counter-ions in the control of crystallite growth. , 2002, Chemical communications.

[38]  Min‐zhao Xue,et al.  Electrochemical Growth of Nanopillar Zinc Oxide Films by Applying a Low Concentration of Zinc Nitrate Precursor , 2006 .

[39]  Dong Lim Kim,et al.  Investigation on the p-type formation mechanism of arsenic doped p-type ZnO thin film , 2006 .

[40]  D. Lincot,et al.  Cathodic electrodeposition of mixed oxide thin films , 2003 .

[41]  Noriko Saito,et al.  Pattern-deposition of light-emitting ZnO particulate film through biomimetic process using self-assembled monolayer template , 2004, Microelectron. J..

[42]  A. Hagfeldt,et al.  Purpose-Built Anisotropic Metal Oxide Material: 3D Highly Oriented Microrod Array of ZnO , 2001 .

[43]  Daniel Lincot,et al.  Mechanistic Study of Cathodic Electrodeposition of Zinc Oxide and Zinc Hydroxychloride Films from Oxygenated Aqueous Zinc Chloride Solutions , 1998 .

[44]  Takashi Omi,et al.  Transparent Zinc Oxide Films Chemically Prepared from Aqueous Solution , 1997 .

[45]  H. Morkoç,et al.  A COMPREHENSIVE REVIEW OF ZNO MATERIALS AND DEVICES , 2005 .

[46]  Y. Liu,et al.  White-light emission of polyvinyl alcohol/ZnO hybrid nanofibers prepared by electrospinning , 2005 .

[47]  D. West,et al.  Room‐Temperature Lasing Observed from ZnO Nanocolumns Grown by Aqueous Solution Deposition , 2002 .

[48]  Neil C. Simmons,et al.  Directed spatial organization of zinc oxide nanorods. , 2004, Nano letters.

[49]  A. Djurišić,et al.  Stimulated emission in ZnO nanostructures: A time-resolved study. , 2005, The journal of physical chemistry. B.

[50]  Min Lai,et al.  Templated Electrosynthesis of Zinc Oxide Nanorods , 2006 .

[51]  D. Lincot,et al.  Oxygen reduction reaction on electrodeposited zinc oxide electrodes in KCl solution at 70 ◦ C , 2006 .

[52]  G. Zou,et al.  In situ growth of ZnO nanocrystals from solid electrospun nanofiber matrixes. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[53]  T. Pauporté,et al.  Hybrid layers of ZnO/lanthanide complexes with high visible luminescences , 2006 .

[54]  E. Fitzgerald,et al.  The effect of post-annealing treatment on photoluminescence of ZnO nanorods prepared by hydrothermal synthesis , 2006 .

[55]  Lian Gao,et al.  Synthesis of uniform rod-like, multi-pod-like ZnO whiskers and their photoluminescence properties , 2004 .

[56]  Daniel Lincot,et al.  One-step electrodeposition of ZnO/eosin Y hybrid films from a hydrogen peroxide oxygen precursor , 2002 .

[57]  Heinz Kalt,et al.  ZnO rediscovered — once again!? , 2005 .

[58]  Xiaomei Wang,et al.  Engineering white light-emitting Eu-doped ZnO urchins by biopolymer-assisted hydrothermal method , 2006 .

[59]  Tsukasa Yoshida,et al.  Improved photoelectrochemical performance of electrodeposited ZnO/EosinY hybrid thin films by dye re-adsorption. , 2004, Chemical communications.

[60]  J H Xiang,et al.  Flexible solar-cell from zinc oxide nanocrystalline sheets self-assembled by an in-situ electrodeposition process. , 2006, Journal of nanoscience and nanotechnology.

[61]  J. Jie,et al.  Non-aqueous cathodic electrodeposition of large-scale uniform ZnO nanowire arrays embedded in anodic alumina membrane , 2005 .

[62]  Weizhuo Zhong,et al.  Growth mechanism and growth habit of oxide crystals , 1999 .

[63]  Annealing effect on optical properties of ZnO films fabricated by cathodic electrodeposition , 2005 .

[64]  Deren Yang,et al.  Low-temperature growth of uniform ZnO particles with controllable ellipsoidal morphologies and characteristic luminescence patterns. , 2006, The journal of physical chemistry. B.

[65]  Gyu-Chul Yi,et al.  Excitonic emissions observed in ZnO single crystal nanorods , 2003 .

[66]  D. Lincot,et al.  Temperature effects on ZnO electrodeposition , 2005 .

[67]  Lisha Zhang,et al.  Low temperature cathodic electrodeposition of nanocrystalline zinc oxide thin films , 2005 .

[68]  Vertically well-aligned ZnO nanowires generated with self-assembling polymers , 2005 .

[69]  M. Jafelicci,et al.  Europium(III)-containing zinc oxide from Pechini method , 2002 .

[70]  W. Ge,et al.  Temperature-dependent photoluminescence of ZnO nanorods prepared by a simple solution route , 2007 .

[71]  D. Lincot,et al.  Electrodeposition of Inorganic/Organic Hybrid Thin Films , 2009 .

[72]  H. Zeng,et al.  Morphology evolution and photoluminescence properties of ZnO films electrochemically deposited on conductive glass substrates , 2006 .

[73]  J. Choy,et al.  Soft Solution Route to Directionally Grown ZnO Nanorod Arrays on Si Wafer; Room‐Temperature Ultraviolet Laser , 2003 .

[74]  Bruno K. Meyer,et al.  Oxygen vacancies in ZnO , 2003 .

[75]  K. Koumoto,et al.  Site-selective deposition and morphology control of UV- and visible-light-emitting ZnO crystals , 2006 .

[76]  Cesare Soci,et al.  Rational synthesis of p-type zinc oxide nanowire arrays using simple chemical vapor deposition. , 2007, Nano letters.

[77]  Y. Liu,et al.  The effect of surface properties on visible luminescence of nanosized colloidal ZnO membranes. , 2005, Journal of colloid and interface science.

[78]  D. Lincot,et al.  Electrodeposition of semiconductors for optoelectronic devices: results on zinc oxide , 2000 .

[79]  Y. Liu,et al.  Hole transport in p-type ZnO films grown by plasma-assisted molecular beam epitaxy , 2006 .

[80]  Subhananda Chakrabarti,et al.  P-type nitrogen- and phosphorus-doped ZnO thin films grown by pulsed laser deposition on sapphire substrates , 2007, SPIE OPTO.

[81]  D. Lincot,et al.  Nanostructured zinc oxide–chromophore hybrid films with multicolored electrochromic properties , 2005 .

[82]  Takashi Sekiguchi,et al.  Hydrothermal growth of ZnO single crystals and their optical characterization , 2000 .

[83]  D. Lincot,et al.  Cathodic electrodeposition from aqueous solution of dense or open‐structured zinc oxide films , 1996 .

[84]  Margaret A. K. Ryan,et al.  CdSe‐Sensitized p‐CuSCN/Nanowire n‐ZnO Heterojunctions , 2005 .

[85]  Wenzhong Shen,et al.  Fabrication and optical properties of large-scale uniform zinc oxide nanowire arrays by one-step electrochemical deposition technique , 2002 .

[86]  Hongwei Song,et al.  Hydrothermal synthesis and photoluminescent properties of ZnO nanorods , 2007 .

[87]  W. Peng,et al.  Structure and visible luminescence of ZnO nanoparticles , 2006 .

[88]  A. Katty,et al.  A new CdTe/ZnO columnar composite film for Eta-solar cells , 2002 .

[89]  Y. Qian,et al.  Controlled synthesis of ZnO nanocrystals with column-, rosette-and fiber-like morphologies and their photoluminescence property , 2004 .

[90]  L. N. Dem’yanets,et al.  Hydrothermal synthesis and cathodoluminescence of ZnO crystalline powders and coatings , 2006 .

[91]  B. Meyer,et al.  The Oxygen Vacancy as the Origin of a Green Emission in Undoped ZnO , 2001 .

[92]  P. O’Brien,et al.  Understanding the factors that govern the deposition and morphology of thin films of ZnO from aqueous solution , 2004 .

[93]  M. Izaki,et al.  Characterization of Transparent Zinc Oxide Films Prepared by Electrochemical Reaction , 1997 .

[94]  M. Imaizumi,et al.  Incorporation of boron in ZnO film from an aqueous solution containing zinc nitrate and dimethylamine-borane by electrochemical reaction , 2002 .

[95]  Shunchong Wang,et al.  Controllable growth and optical properties of large scale ZnO arrays , 2005 .

[96]  Claude Lévy-Clément,et al.  ZnO/CdTe/CuSCN, a promising heterostructure to act as inorganic eta-solar cell , 2005 .

[97]  Hongyu Guan,et al.  Preparation and characterization of ZnO nanofibers by using electrospun PVA/zinc acetate composite fiber as precursor , 2004 .

[98]  M. Izaki,et al.  Room-temperature ultraviolet light-emitting zinc oxide micropatterns prepared by low-temperature electrodeposition and photoresist , 2003 .

[99]  Sigurd Wagner,et al.  Thin film semiconductor deposition on free-standing ZnO columns , 2000 .

[100]  Jonathan C. Knowles,et al.  Speciation and the nature of ZnO thin films from chemical bath deposition , 1996 .

[101]  Masanobu Izaki,et al.  Characterization of Boron‐Incorporated Zinc Oxide Film Chemically Prepared from an Aqueous Solution , 2000 .

[102]  D. Lincot,et al.  Mechanistic study of the electrodeposition of nanoporous self-assembled ZnO/Eosin Y hybrid thin films: effect of eosin concentration. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[103]  Huifang Xu,et al.  Complex and oriented ZnO nanostructures , 2003, Nature materials.

[104]  Zhong Lin Wang Zinc oxide nanostructures: growth, properties and applications , 2004 .

[105]  L. Vayssieres Growth of Arrayed Nanorods and Nanowires of ZnO from Aqueous Solutions , 2003 .

[106]  M. Grätzel,et al.  A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films , 1991, Nature.

[107]  Daniel Lincot,et al.  Toward laser emission of epitaxial nanorod arrays of ZnO grown by electrodeposition , 2006 .

[108]  J. Rathouský,et al.  Electrodeposited Mesoporous ZnO Thin Films as Efficient Photocatalysts for the Degradation of Dye Pollutants , 2007 .

[109]  C. Schlegel,et al.  Vertical nanowire light-emitting diode , 2004 .

[110]  M. Izaki,et al.  Transparent zinc oxide films prepared by electrochemical reaction , 1996 .

[111]  G. Y. Wang,et al.  Structure study of electrodeposited ZnO nanowires , 2005, Microelectron. J..

[112]  D. Lincot,et al.  Preparation of ZnO/Eu mixed films by electrochemical precipitation , 2007 .

[113]  David P. Norton,et al.  ZnO nanowire growth and devices , 2004 .

[114]  R. Könenkamp,et al.  Ultraviolet electroluminescence from ZnO/polymer heterojunction light-emitting diodes. , 2005, Nano letters.

[115]  Zhong Lin Wang Nanostructures of zinc oxide , 2004 .

[116]  M. Izaki,et al.  Influence of ( CH 3 ) 2 NHBH 3 Concentration on Electrical Properties of Electrochemically Grown ZnO Films , 2001 .

[117]  Kam Sing Wong,et al.  Microcavity lasing behavior of oriented hexagonal ZnO nanowhiskers grown by hydrothermal oxidation , 2004 .

[118]  D. Lincot,et al.  Hydrogen peroxide oxygen precursor for zinc oxide electrodeposition II—Mechanistic aspects , 2001 .

[119]  M. Meyyappan,et al.  Growth of Epitaxial Nanowires at the Junctions of Nanowalls , 2003, Science.

[120]  Daniel Lincot,et al.  A ZnO nanowire array film with stable highly water-repellent properties , 2007 .

[121]  Frank Lenzmann,et al.  A Solid-State Dye-Sensitized Solar Cell Fabricated with Pressure-Treated P25−TiO2 and CuSCN: Analysis of Pore Filling and IV Characteristics , 2002 .

[122]  D. Lincot,et al.  In situ ESR and UV/vis spectroelectrochemical study of eosin Y upon reduction with and without Zn(II) ions. , 2007, Chemphyschem : a European journal of chemical physics and physical chemistry.

[123]  M. Davolos,et al.  Pechini's solution as precursor for Eu(III)-containing ZnO films , 2003 .

[124]  S. Lis Luminescence spectroscopy of lanthanide(III) ions in solution , 2002 .

[125]  H. Minoura,et al.  Mechanism of cathodic electrodeposition of zinc oxide thin films from aqueous zinc nitrate baths , 2004 .

[126]  L. Gao,et al.  Wet chemical synthesis of ultralong and straight single-crystalline ZnO nanowires and their excellent UV emission properties , 2003 .

[127]  J. Jiménez,et al.  Cathodoluminescence characterization of hydrothermal ZnO crystals , 2005 .

[128]  T. Pauporté,et al.  Highly Porous Electrodeposited Zinc Oxide Films Functionalized for Red∕Green Luminescence , 2006 .

[129]  D. Lincot,et al.  Hydrogen Peroxide Oxygen Precursor for Zinc Oxide Electrodeposition I. Deposition in Perchlorate Medium , 2001 .

[130]  Zhong Lin Wang,et al.  Nanobelts of Semiconducting Oxides , 2001, Science.

[131]  D. Hwang,et al.  Effect of annealing temperature and ambient gas on phosphorus doped p-type ZnO , 2007 .

[132]  N. Pesika,et al.  Determination of the Particle Size Distribution of Quantum Nanocrystals from Absorbance Spectra , 2003 .

[133]  V. Nikitenko Optics and Spectroscopy of Point Defects in ZnO , 2005 .

[134]  A. Djurišić,et al.  Defects in ZnO nanorods prepared by a hydrothermal method. , 2006, The journal of physical chemistry. B.

[135]  Kazuo Ito,et al.  Preparation of ZnO thin films using the flowing liquid film method , 1996 .

[136]  Jay A. Switzer,et al.  Epitaxial Electrodeposition of Zinc Oxide Nanopillars on Single-Crystal Gold , 2001 .

[137]  F. A. Reis,et al.  Statistical modelling of electrochemical deposition of nanostructured hybrid films with ZnO-Eosin Y as a case example , 2006 .

[138]  William L. Warren,et al.  Correlation between photoluminescence and oxygen vacancies in ZnO phosphors , 1996 .