Evidence of Filamentary Switching in Oxide-based Memory Devices via Weak Programming and Retention Failure Analysis

Further progress in high-performance microelectronic devices relies on the development of novel materials and device architectures. However, the components and designs that are currently in use have reached their physical limits. Intensive research efforts, ranging from device fabrication to performance evaluation, are required to surmount these limitations. In this paper, we demonstrate that the superior bipolar resistive switching characteristics of a CeO2:Gd-based memory device can be manipulated by means of UV radiation, serving as a new degree of freedom. Furthermore, the metal oxide-based (CeO2:Gd) memory device was found to possess electrical and neuromorphic multifunctionalities. To investigate the underlying switching mechanism of the device, its plasticity behaviour was studied by imposing weak programming conditions. In addition, a short-term to long-term memory transition analogous to the forgetting process in the human brain, which is regarded as a key biological synaptic function for information processing and data storage, was realized. Based on a careful examination of the device’s retention behaviour at elevated temperatures, the filamentary nature of switching in such devices can be understood from a new perspective.

[1]  A. Sawa Resistive switching in transition metal oxides , 2008 .

[2]  Yuchao Yang,et al.  Observation of conducting filament growth in nanoscale resistive memories , 2012, Nature Communications.

[3]  N. Wu,et al.  Evidence for an oxygen diffusion model for the electric pulse induced resistance change effect in transition-metal oxides. , 2006, Physical Review Letters.

[4]  Sean Li,et al.  Interface-engineered resistive switching: CeO(2) nanocubes as high-performance memory cells. , 2013, ACS applied materials & interfaces.

[5]  J. C. Scott,et al.  Nonvolatile Memory Elements Based on Organic Materials , 2007 .

[6]  Maofa Ge,et al.  Enhanced activity of tungsten modified CeO2/TiO2 for selective catalytic reduction of NOx with ammonia , 2010 .

[7]  L. Goux,et al.  Switching mechanism and reverse engineering of low-power Cu-based resistive switching devices. , 2013, Nanoscale.

[8]  P. Hu,et al.  Resistive dependence of magnetic properties in nonvolatile Ti/Mn:TiO2/SrTi0.993Nb0.007O3/Ti memory device , 2009 .

[9]  Min Yang,et al.  Arsenate adsorption on an Fe-Ce bimetal oxide adsorbent: role of surface properties. , 2005, Environmental science & technology.

[10]  Jian Shi,et al.  Colossal resistance switching and band gap modulation in a perovskite nickelate by electron doping , 2014, Nature Communications.

[11]  T. Hasegawa,et al.  Short-term plasticity and long-term potentiation mimicked in single inorganic synapses. , 2011, Nature materials.

[12]  D. Jeong,et al.  Emerging memories: resistive switching mechanisms and current status , 2012, Reports on progress in physics. Physical Society.

[13]  Masateru Taniguchi,et al.  Resistive switching multistate nonvolatile memory effects in a single cobalt oxide nanowire. , 2010, Nano letters.

[14]  Dominique Vuillaume,et al.  Filamentary switching: synaptic plasticity through device volatility. , 2015, ACS nano.

[15]  R. Dittmann,et al.  Redox‐Based Resistive Switching Memories – Nanoionic Mechanisms, Prospects, and Challenges , 2009, Advanced materials.

[16]  Jae Hyuck Jang,et al.  Atomic structure of conducting nanofilaments in TiO2 resistive switching memory. , 2010, Nature nanotechnology.

[17]  Sean Li,et al.  Direct growth of TiO2 nanotubes on transparent substrates and their resistive switching characteristics , 2012 .

[18]  Tae Hyung Park,et al.  Dual Conical Conducting Filament Model in Resistance Switching TiO2 Thin Films , 2015, Scientific Reports.

[19]  Tomoji Kawai,et al.  Resistive-switching memory effects of NiO nanowire/metal junctions. , 2010, Journal of the American Chemical Society.

[20]  K. Terabe,et al.  Quantized conductance atomic switch , 2005, Nature.

[21]  Shinhyun Choi,et al.  Tuning resistive switching characteristics of tantalum oxide memristors through Si doping. , 2014, ACS nano.

[22]  Pablo Stoliar,et al.  A Light‐Controlled Resistive Switching Memory , 2012, Advanced materials.

[23]  R. Stanley Williams,et al.  Electronic structure and transport measurements of amorphous transition-metal oxides: observation of Fermi glass behavior , 2012, Applied Physics A.

[24]  K. Toi,et al.  Oxygen species adsorbed on ultraviolet-irradiated magnesium oxide , 1985 .

[25]  Masakazu Aono,et al.  On-demand nanodevice with electrical and neuromorphic multifunction realized by local ion migration. , 2012, ACS nano.

[26]  Haiyang Peng,et al.  Deterministic conversion between memory and threshold resistive switching via tuning the strong electron correlation , 2012, Scientific Reports.

[27]  Dewei Chu,et al.  High-performance nanocomposite based memristor with controlled quantum dots as charge traps. , 2013, ACS applied materials & interfaces.

[28]  Wei Lu,et al.  Retention failure analysis of metal-oxide based resistive memory , 2014 .

[29]  Wei Lu,et al.  Random telegraph noise and resistance switching analysis of oxide based resistive memory. , 2014, Nanoscale.

[30]  Meilin Liu,et al.  Electron stimulated desorption of O2+ from gadolinia-doped ceria surfaces , 2008 .

[31]  R. Waser,et al.  Switching the electrical resistance of individual dislocations in single-crystalline SrTiO3 , 2006, Nature materials.

[32]  L. Zhang,et al.  Aqueous co-precipitation of Pd-doped cerium oxide nanoparticles: chemistry, structure, and particle growth , 2011, Journal of Materials Science.

[33]  Sean Li,et al.  Voltage sweep modulated conductance quantization in oxide nanocomposites , 2014 .

[34]  Meng-Han Lin,et al.  Improvement of Resistive Switching Characteristics in $\hbox{SrZrO}_{3}$ Thin Films With Embedded Cr Layer , 2008, IEEE Electron Device Letters.