[Ag(70)(PW(9)O(34))(2)((t)BuC[triple bond, length as m-dash]C)(44)(H(2)O)(2)](8+): ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions.

A silver alkynyl cluster containing a Ag70 shell and two lacunary [PW9O34](9-) templating ions was synthesized by an ionothermal approach. Fast core-shell electronic communication between silver(i) centers and polyoxometalates was verified via cyclic voltammetry studies in [BMIm]BF4.

[1]  F. Gao,et al.  A giant metallo-supramolecular cage encapsulating a single-molecule magnet. , 2013, Chemical communications.

[2]  S. Dehnen,et al.  Chalcogenide clusters of copper and silver from silylated chalcogenide sources. , 2013, Chemical Society reviews.

[3]  Shoutian Zheng,et al.  Recent advances in paramagnetic-TM-substituted polyoxometalates (TM = Mn, Fe, Co, Ni, Cu). , 2012, Chemical Society reviews.

[4]  L. Cronin,et al.  Engineering polyoxometalates with emergent properties. , 2012, Chemical Society reviews.

[5]  H. Nogueira,et al.  Organic-inorganic hybrid materials based on iron(III)-polyoxotungstates and 1-butyl-3-methylimidazolium cations. , 2012, Dalton transactions.

[6]  Yang-guang Li,et al.  An ionothermal synthetic approach to porous polyoxometalate-based metal-organic frameworks. , 2012, Angewandte Chemie.

[7]  Z. Su,et al.  Assembly of a luminescent core-shell nanocluster featuring a Ag34S26 shell and a W6O21(6-) polyoxoanion core. , 2012, Chemical communications.

[8]  E. Ahmed,et al.  Ionothermal synthesis of polyoxometalates. , 2012, Angewandte Chemie.

[9]  T. Mak,et al.  A pyrovanadate-templated silver(I)-ethynide cluster circumscribed by macrocyclic polyoxovanadate(V). , 2012, Chemical communications.

[10]  L. Cronin,et al.  Silver linked polyoxometalate open frameworks (Ag-POMOFs) for the directed fabrication of silver nanomaterials , 2011 .

[11]  T. Mak,et al.  Silver(I)-ethynide clusters constructed with phosphonate-functionized polyoxovanadates. , 2011, Journal of the American Chemical Society.

[12]  Yang-guang Li,et al.  Polyoxometalate-Based Metal−Organic Frameworks Assembled under the Ionothermal Conditions , 2011 .

[13]  S. Krivovichev,et al.  Ionothermal synthesis and characterization of alkali metal polyoxometallates: Structural trends in t , 2010 .

[14]  L. Cronin,et al.  Assembly of Pure Silver‐Tungsten‐Oxide Frameworks from Nanostructured Solution Processable Clusters and Their Evolution into Materials with a Metallic Component , 2010, Advanced materials.

[15]  M. Jansen,et al.  {[Ag42(CO3)(C[triple bond]CtBu)27(CH3CN)2][CoW12O40]2}[BF4]: an intercluster sandwich compound. , 2010, Angewandte Chemie.

[16]  J. Qiao,et al.  A giant silver alkynyl cage with sixty silver(I) ions clustered around polyoxometalate templates. , 2010, Angewandte Chemie.

[17]  Yang-guang Li,et al.  Preparation of polyoxometalates in ionic liquids by ionothermal synthesis. , 2010, Dalton transactions.

[18]  Guanggang Gao,et al.  Acid-induced surface functionalization of polyoxometalate by enclosure in a polyhedral silver-alkynyl cage. , 2009, Journal of the American Chemical Society.

[19]  N. Gadegaard,et al.  Supramolecular silver polyoxometalate architectures direct the growth of composite semiconducting nanostructures. , 2009, Angewandte Chemie.

[20]  Bruno Scrosati,et al.  Ionic-liquid materials for the electrochemical challenges of the future. , 2009, Nature materials.

[21]  Leroy Cronin,et al.  Modular assembly of a functional polyoxometalate-based open framework constructed from unsupported AgI--AgI interactions. , 2007, Angewandte Chemie.

[22]  Andrew J. P. White,et al.  Anion-Templated Syntheses of Rhombohedral Silver-Alkynyl Cage Compounds. , 2001, Angewandte Chemie.