Microstructure and mechanical properties of Al-7Si-0.7Mg alloy formed with an addition of (Pr+Ce)

Abstract Effects of (Pr+Ce) addition on the Al-7Si-0.7Mg alloy were investigated by optical microscope (OM), energy diffraction spectrum (EDS), X-ray diffraction (XRD) and tensile tests. The results showed that the Al-7Si-0.7Mg alloy was modified with (Pr+Ce) addition. The needle-like eutectic silicon phase developed into rose form and the crystalline grains decreased in size and showed a high degree of spheroidization. When the amount of the (Pr+Ce) addition reached 0.6 wt.%, the mean diameter was 31.8 μm (refined by 50%). The aspect ratio decreased to 1.35, and the tensile strength and ductility reached 192.4 MPa and 2.18%, respectively. At higher levels of addition, over-modification occurred, as indicated by increased grain size and reduced mechanical properties. The poisoning effect of the (Pr+Ce) addition on eutectic silicon and the constitutional supercooling caused by the (Pr+Ce) addition were the major causes of alloy modification, grain refinement, and the improvement of mechanical properties.

[1]  Dai Hong METASTABLE EXTENSION OF SOLID SOLUBILITY OF RARE-EARTH ELEMENTS IN Al , 1992 .

[2]  Erjun Guo,et al.  Modification effect of lanthanum on primary phase Mg2Si in Mg-Si alloys , 2008 .

[3]  Yan Hong,et al.  Effect of samarium (Sm) addition on the microstructures and mechanical properties of Al–7Si–0.7Mg alloys , 2013 .

[4]  Qudong Wang,et al.  A new high-strength and corrosion-resistant Al–Si based casting alloy , 2013 .

[5]  V. Vijayan,et al.  Effect of chilling and cerium addition on microstructure and cooling curve parameters of Al–14%Si alloy , 2015 .

[6]  J. Shin,et al.  Microstructure refining of aluminum alloys using aluminothermic reaction with ZnO nanoparticles , 2015 .

[7]  Hong Yan,et al.  Modification of primary α-Al, eutectic silicon and β-Al5FeSi phases in as-cast AlSi10Cu3 alloys with (La+Yb) addition , 2015 .

[8]  W. Xiao,et al.  The effect of scandium addition on microstructure and mechanical properties of Al–Si–Mg alloy: A multi-refinement modifier , 2015 .

[9]  A. K. Dahle,et al.  Eutectic Modification of Al-Si Alloys with Rare Earth Metals , 2004 .

[10]  Hong Yan,et al.  Preparation of Al–La master alloy by ultrasonic method and modification on Al alloy , 2015, Rare Metals.

[11]  Yan Hon Effect of Lanthanum on Microstructure of ADC12 Aluminum Alloy Solid Solution and Aging Treatments , 2013 .

[12]  K. Gschneidner,et al.  The Al−Re (Aluminum-Rare earth) systems , 1988 .

[13]  Hong Yan,et al.  Effect of trace La addition on the microstructure and mechanical property of as-cast ADC12 Al-Alloy , 2013, Journal of Wuhan University of Technology-Mater. Sci. Ed..

[14]  Xiaowu Hu,et al.  Effects of rare earth Er additions on microstructure development and mechanical properties of die-cast ADC12 aluminum alloy , 2012 .

[15]  Hong Yan,et al.  Modification of eutectic silicon and β-Al5FeSi phases in as-cast ADC12 alloys by using samarium addition , 2013 .

[16]  A. Samuel,et al.  The effects of mischmetal, cooling rate and heat treatment on the eutectic Si particle characteristics of A319.1, A356.2 and A413.1 Al-Si casting alloys , 2008 .