The reactivity of o-amidophenolate indium(III) complexes towards different oxidants

The reactivity of o-amidophenolate indium(III) complexes towards different oxidants was investigated. The oxidation reactions were found to proceed through the stage of paramagnetic o-iminobenzosemiquinonato indium(III) derivative formation. The monoradical intermediates undergo symmetrization. The final products of the oxidation processes are corresponding biradical o-iminobenzosemiquinonato indium(III) complexes. In order to understand the reasons for the symmetrization processes steric factors (G-parameters) were evaluated for all intermediates and final products by a method based on the ligand solid angle approach.

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