Green chemistry, biorefineries and second generation strategies for re-use of waste: an overview

Abstract: Today fossil resources supply 86% of our energy and 96% of organic chemicals. Future petroleum production is unlikely to meet our society’s growing needs. Green chemistry is an area which is attracting increasing interest as it provides unique opportunities for innovation via use of clean and green technologies, product substitution and the use of renewable feedstocks such as dedicated crops or food supply chain by-products for the production of bio-derived chemicals, materials and fuels. This chapter provides an introduction to the concepts of green chemistry and the biorefinery and, based on examples, discusses second generation re-use of waste and by-products as feedstocks for the biorefinery.

[1]  P. Anastas,et al.  Green Chemistry , 2018, Environmental Science.

[2]  J. Litchfield Microbiological and enzymatic treatments for utilizing agricultural and food processing wastes , 1987 .

[3]  J. F. Deye,et al.  Nile Red as a solvatochromic dye for measuring solvent strength in normal liquids and mixtures of normal liquids with supercritical and near critical fluids , 1990 .

[4]  C. Zaror Controlling the environmental impact of the food industry: an integral approach , 1992 .

[5]  M. Infante,et al.  Lipopeptidic surfactants. II. Acidic and basic Nα-lauroyl-L-arginine dipeptides from pure amino acids , 1992 .

[6]  V. Vaks,et al.  Dissociation of water by microwave radiation , 1994 .

[7]  G. Kroyer Impact of food processing on the environment—an overview , 1995 .

[8]  S. M. Schaub,et al.  Composting: An alternative waste management option for food processing industries , 1996 .

[9]  A. Schecter A selective historical review of congener-specific human tissue measurements as sensitive and specific biomarkers of exposure to dioxins and related compounds. , 1998, Environmental health perspectives.

[10]  Paul T. Anastas,et al.  Life cycle assessment and green chemistry: the yin and yang of industrial ecology , 2000 .

[11]  P. Anastas,et al.  Green Chemical Syntheses and Processes: Introduction , 2000 .

[12]  C. Graham,et al.  Cardiac autonomic control mechanisms in power-frequency magnetic fields: a multistudy analysis. , 2000, Environmental health perspectives.

[13]  R. Carle,et al.  By-products of plant food processing as a source of functional compounds — recent developments , 2001 .

[14]  Paul T Anastas,et al.  Origins, current status, and future challenges of green chemistry. , 2002, Accounts of chemical research.

[15]  Günther Laufenberg,et al.  Transformation of vegetable waste into value added products: (A) the upgrading concept; (B) practical implementations. , 2003, Bioresource technology.

[16]  B. Kamm,et al.  Principles of biorefineries , 2004, Applied Microbiology and Biotechnology.

[17]  T. Welton Ionic liquids in catalysis , 2004 .

[18]  R. Elander,et al.  Process and economic analysis of pretreatment technologies. , 2005, Bioresource technology.

[19]  M. G. Kulkarni,et al.  WASTE COOKING OIL – AN ECONOMICAL SOURCE FOR BIODIESEL: A REVIEW , 2006 .

[20]  Charlotte K. Williams,et al.  The Path Forward for Biofuels and Biomaterials , 2006, Science.

[21]  A. J. Hunt,et al.  Green chemistry and the biorefinery: a partnership for a sustainable future , 2006 .

[22]  Wieland Peschel,et al.  An industrial approach in the search of natural antioxidants from vegetable and fruit wastes , 2006 .

[23]  Paul M. Rose,et al.  The fractionation of valuable wax products from wheat straw using CO2 , 2006 .

[24]  R. A. Davis Parameter Estimation for Simultaneous Saccharification and Fermentation of Food Waste Into Ethanol Using Matlab Simulink , 2008, Applied biochemistry and biotechnology.

[25]  J. Clark,et al.  The integration of green chemistry into future biorefineries. , 2009 .

[26]  Ioannis V. Skiadas,et al.  Toward a common classification approach for biorefinery systems , 2009 .

[27]  Joseph B. Binder,et al.  Simple chemical transformation of lignocellulosic biomass into furans for fuels and chemicals. , 2009, Journal of the American Chemical Society.

[28]  Ashley J. Wilson,et al.  The preparation of high-grade bio-oils through the controlled, low temperature microwave activation of wheat straw. , 2009, Bioresource technology.

[29]  S. Giljum,et al.  Overconsumption? Our use of the world's natural resources , 2009 .

[30]  F. Sahena,et al.  Application of supercritical CO2 in lipid extraction – A review , 2009 .

[31]  Norberto Fueyo,et al.  An estimation of the energy potential of agro-industrial residues in Spain , 2010 .

[32]  Francesco Cherubini,et al.  The biorefinery concept: Using biomass instead of oil for producing energy and chemicals , 2010 .

[33]  J. Parfitt,et al.  Food waste within food supply chains: quantification and potential for change to 2050 , 2010, Philosophical Transactions of the Royal Society B: Biological Sciences.

[34]  Hefa Cheng,et al.  Municipal solid waste (MSW) as a renewable source of energy: current and future practices in China. , 2010, Bioresource technology.

[35]  S. Papanikolaou,et al.  Cheese whey as a renewable substrate for microbial lipid and biomass production by Zygomycetes , 2010 .

[36]  J. Clark,et al.  Microwave assisted decomposition of cellulose: A new thermochemical route for biomass exploitation. , 2010, Bioresource technology.

[37]  Younis Jamal,et al.  Production of biodiesel: A technical review , 2011 .

[38]  Steven R. Thomas,et al.  Process and technoeconomic analysis of leading pretreatment technologies for lignocellulosic ethanol production using switchgrass. , 2011, Bioresource technology.

[39]  A. J. Hunt,et al.  Use of green chemical technologies in an integrated biorefinery , 2011 .

[40]  J. A. Menéndez,et al.  Microwave Heating Applied to Pyrolysis , 2011 .

[41]  Andreas Brekke,et al.  Environmental Impacts and Costs of Hydrotreated Vegetable Oils, Transesterified Lipids and Woody BTL—A Review , 2011 .

[42]  A. J. Hunt,et al.  The chemical value of wheat straw combustion residues , 2011 .

[43]  A. J. Hunt,et al.  Supercritical fluid extraction (SFE) as an effective tool in reducing auto-oxidation of dried pine sawdust for power generation , 2012 .

[44]  M. Simon,et al.  Green chemistry oriented organic synthesis in water. , 2012, Chemical Society reviews.

[45]  A. J. Hunt,et al.  Elemental sustainability: Towards the total recovery of scarce metals , 2012 .