Effect of graphite sizes and carbon nanotubes content on flowability of bulk-molding compound and formability of the composite bipolar plate for fuel cell

Abstract This study investigates the flowability of the bulk-molding compound (BMC) on composite bipolar plates containing graphite content from 70 to 80 wt% with different graphite sizes. A small quantity (from 0.25 to 2 wt%) of multi-walled carbon nanotubes (MWCNT) is also added. Findings show that the flowability of BMC material decreases with decreasing graphite size and with increasing graphite content. The BMC material containing large size graphite (177–125 μm) entirely exhibits a relatively higher flowability within the analysis graphite contents, in the range of 73.3–11.3 cm, compared to the small size (74–45 μm), in which flowability is in the range of 40.3–6.67 cm. Further adding MWCNT causes decreased flowability of the BMC material especially when the percolated networking structure is formed through the resin. Therefore, with flowability below 10 cm, the formability of a large area (300 mm × 300 mm × 3 mm) or thin (100 mm × 100 mm × 0.5 mm) composite bipolar plate shows a large area of surface porosity or visible defects. Results indicate that the flowability of the thermoset-based BMC material is an important design parameter to fabricate cost-effective, large, or thin composite bipolar plates.

[1]  J. Mcgrath,et al.  Development of fuel cell bipolar plates from graphite filled wet-lay thermoplastic composite materials , 2005 .

[2]  Andrew Dicks,et al.  The role of carbon in fuel cells , 2006 .

[3]  H. Lee,et al.  Dynamic mechanical and morphological properties of polycarbonate/multi-walled carbon nanotube composites , 2005 .

[4]  Leon L. Shaw,et al.  On the improved properties of injection-molded, carbon nanotube-filled PET/PVDF blends , 2004 .

[5]  Sanjeev Mukerjee,et al.  Effects of Nafion impregnation on performances of PEMFC electrodes , 1998 .

[6]  S. Iijima Helical microtubules of graphitic carbon , 1991, Nature.

[7]  Hsu-Chiang Kuan,et al.  Preparation, electrical, mechanical and thermal properties of composite bipolar plate for a fuel cell , 2004 .

[8]  Paul Leonard Adcock,et al.  Bipolar plate materials for solid polymer fuel cells , 2000 .

[9]  A. Su,et al.  Preparation and properties of functionalized multiwalled carbon nanotubes/polypropylene nanocomposite bipolar plates for polymer electrolyte membrane fuel cells , 2010 .

[10]  Osamu Kobayashi,et al.  Mass production cost of PEM fuel cell by learning curve , 2004 .

[11]  Wei Zhou,et al.  Nanotube Networks in Polymer Nanocomposites: Rheology and Electrical Conductivity , 2004 .

[12]  Dai Gil Lee,et al.  Bipolar plate made of carbon fiber epoxy composite for polymer electrolyte membrane fuel cells , 2008 .

[13]  A. Su,et al.  One-step functionalization of carbon nanotubes by free-radical modification for the preparation of nanocomposite bipolar plates in polymer electrolyte membrane fuel cells , 2008 .

[14]  T. L. Dhami,et al.  Development and Characterization of Expanded Graphite-Based Nanocomposite as Bipolar Plate for Polymer Electrolyte Membrane Fuel Cells (PEMFCs) , 2008 .

[15]  Chen-Chi M. Ma,et al.  Preparation and properties of high performance nanocomposite bipolar plate for fuel cell , 2006 .

[16]  Jaafar Sahari,et al.  Electrical properties of carbon-based polypropylene composites for bipolar plates in polymer electrolyte membrane fuel cell (PEMFC) , 2007 .

[17]  Chen-Chi M. Ma,et al.  Preparation and properties of carbon nanotube-reinforced vinyl ester/nanocomposite bipolar plates for polymer electrolyte membrane fuel cells , 2008 .

[18]  Shuo-Jen Lee,et al.  Preparation and properties of carbon nanotube/polypropylene nanocomposite bipolar plates for polymer electrolyte membrane fuel cells , 2008 .

[19]  S. Redner,et al.  Introduction To Percolation Theory , 2018 .

[20]  M. Abdel-Goad,et al.  Rheological characterization of melt processed polycarbonate-multiwalled carbon nanotube composites , 2005 .

[21]  Aiju Li,et al.  Study on carbon nanotube reinforced phenol formaldehyde resin/graphite composite for bipolar plate , 2008 .

[22]  S. Jana,et al.  Highly conductive epoxy/graphite composites for bipolar plates in proton exchange membrane fuel cells , 2007 .

[23]  James F. Miller,et al.  Challenges for fuel cells in transport applications , 2000 .

[24]  D. Baird,et al.  Development of bipolar plates for fuel cells from graphite filled wet-lay material and a thermoplastic laminate skin layer , 2007 .

[25]  C. Hong,et al.  Effect of carbon fillers on properties of polymer composite bipolar plates of fuel cells , 2009 .

[26]  Rakesh B. Mathur,et al.  Fabrication of high strength and a low weight composite bipolar plate for fuel cell applications , 2007 .

[27]  Isa Bar-On,et al.  Technical cost analysis for PEM fuel cells , 2002 .