Semipolar GaN‐based heterostructures on foreign substrates

This paper reviews our recent investigations about semipolar GaN-based optoelectronic heterostructures grown on foreign substrates. Two basically different approaches are discussed, both making use of epitaxial growth in the polar c-direction to minimize any crystalline defects. By selective area growth, stripes with triangular cross-section have been formed with semipolar side-facets, on which quantum well and electroluminescence test structures have been deposited. By careful optimisation of many growth parameters, we could drastically increase the growth temperature of GaInN quantum wells emitting beyond 500 nm. In the second approach, the GaN growth starts on inclined sapphire c-planes, which form the side facets of trenches etched into the substrates. After coalescence, planar semipolar GaN layers can be achieved. We investigated various sapphire wafer orientations leading to {112‾2}, {101‾1}, and {202‾1} layers. After careful optimisation with a major focus on the decrease of the stacking fault density, we have also investigated the doping behaviour of such semipolar structures. Eventually, full electroluminescence test structures could be grown.

[1]  K. Thonke,et al.  Ga(In)N Photonic Crystal Light Emitters with Semipolar Quantum Wells , 2013 .

[2]  Dominik Heinz,et al.  Internal quantum efficiency and carrier injection efficiency of c‐plane, {101‾1} and {112‾2} InGaN/GaN‐based light‐emitting diodes , 2015 .

[3]  Yoshio Honda,et al.  Growth of ( 1 1 0 1 ) GaN on a 7-degree off-oriented (0 0 1)Si substrate by selective MOVPE , 2002 .

[4]  GaN based LEDs with semipolar QWs employing embedded sub-micrometer sized selectively grown 3D structures , 2013 .

[5]  C. Q. Chen,et al.  Luminescence from stacking faults in gallium nitride , 2005 .

[6]  Koji Katayama,et al.  Continuous-Wave Operation of 520 nm Green InGaN-Based Laser Diodes on Semi-Polar {2021} GaN Substrates , 2009 .

[7]  Umesh K. Mishra,et al.  Growth of bulk InGaN films and quantum wells by atmospheric pressure metalorganic chemical vapour deposition , 1997 .

[8]  Sébastien Chenot,et al.  Semipolar GaN films on patterned r-plane sapphire obtained by wet chemical etching , 2010 .

[9]  Ferdinand Scholz,et al.  Improvements of MOVPE grown (11$ \bar 2 $2) oriented GaN on pre‐structured sapphire substrates using a SiNx interlayer and HVPE overgrowth , 2014 .

[10]  K. Thonke,et al.  INGAN/GAN based semipolar green converters , 2013 .

[11]  Lutz Kirste,et al.  Diffusion of Mg dopant in metal-organic vapor-phase epitaxy grown GaN and AlxGa1−xN , 2013 .

[12]  Yoshio Honda,et al.  Optical and Electrical Properties of (1-101)GaN Grown on a 7°Off-Axis (001)Si Substrate , 2004 .

[13]  K. Thonke,et al.  Doping behavior of (112‾2) GaN grown on patterned sapphire substrates , 2016 .

[14]  Gerald B. Stringfellow,et al.  Solid phase immiscibility in GaInN , 1996 .

[15]  Ferdinand Scholz,et al.  EBIC investigations on polar and semipolar InGaN LED structures , 2016 .

[16]  K. Yamane,et al.  High-quality {20-21} GaN layers on patterned sapphire substrate with wide-terrace , 2011 .

[17]  T. Wunderer,et al.  Three‐dimensional GaN for semipolar light emitters , 2011 .

[18]  Sebastian Metzner,et al.  Growth and coalescence behavior of semipolar $(11{\bar {2}}2)$ GaN on pre‐structured r‐plane sapphire substrates , 2011 .

[19]  Tobias Meyer,et al.  Green high‐power light sources using InGaN multi‐quantum‐well structures for full conversion , 2011 .

[20]  K. Fujito,et al.  Development of Bulk GaN Crystals and Nonpolar/Semipolar Substrates by HVPE , 2009 .

[21]  K. Thonke,et al.  Spectroscopic study of semipolar (112¯2)-HVPE GaN exhibiting high oxygen incorporation , 2014 .

[22]  J. Hertkorn,et al.  Process optimization for the effective reduction of threading dislocations in MOVPE grown GaN using in situ deposited SiNx masks , 2008 .

[23]  Mg doping of 3D semipolar InGaN/GaN‐based light emitting diodes , 2014 .

[24]  N. Okada,et al.  Growth of Semipolar (112̄2) GaN Layer by Controlling Anisotropic Growth Rates in r-Plane Patterned Sapphire Substrate , 2009 .

[25]  Sebastian Metzner,et al.  Semipolar GaInN/GaN light- emitting diodes grown on honeycomb patterned substrates , 2010 .

[26]  Detlef Hommel,et al.  High-quality bulk a-plane GaN sliced from boules in comparison to heteroepitaxially grown thick films on r-plane sapphire , 2006 .

[27]  Ferdinand Scholz,et al.  GaInN quantum wells grown on facets of selectively grown GaN stripes , 2005 .

[28]  S. Nakamura Current Status of GaN-Based Solid-State Lighting , 2009 .

[29]  F. Scholz,et al.  HVPE growth of high quality GaN layers , 2006 .

[30]  K. Thonke,et al.  Semipolar GaInN quantum well structures on large area substrates , 2012 .

[31]  T. Wunderer,et al.  Time- and locally resolved photoluminescence of semipolar GaInN∕GaN facet light emitting diodes , 2007 .

[32]  T. Meisch,et al.  (20$ \bar 2 $1) MOVPE and HVPE GaN grown on 2″ patterned sapphire substrates , 2014 .

[33]  Ferdinand Scholz,et al.  Growth and coalescence studies of (112‾2) oriented GaN on pre‐structured sapphire substrates using marker layers , 2016 .

[34]  K. Thonke,et al.  Three‐dimensional reciprocal space mapping of diffuse scattering for the study of stacking faults in semipolar () GaN layers grown from the sidewall of an r‐patterned sapphire substrate , 2013 .

[35]  Embedded GaN nanostripes on c‐sapphire for DFB lasers with semipolar quantum wells , 2016 .

[36]  M. Aoki,et al.  Influence of 3d-Transition-Metal Additives on Single Crystal Growth of GaN by the Na Flux Method , 2003 .

[37]  T. Wunderer,et al.  Semipolar GaN/GaInN LEDs with more than 1 mW optical output power , 2007 .

[38]  F. Scholz,et al.  An Oxygen Doped Nucleation Layer for the Growth of High Optical Quality GaN on Sapphire , 2001 .

[39]  Kanglin Xiong,et al.  Semipolar (20 2¯1) GaN and InGaN quantum wells on sapphire substrates , 2014 .

[40]  T. Wunderer,et al.  Planar semipolar (101¯1) GaN on (112¯3) sapphire , 2010 .

[41]  U J Gibson,et al.  Simple versatile method for fabricating guided-wave gratings. , 1985, Applied optics.

[42]  K. Nishiyama,et al.  Recent Progress in Selective Area Growth and Epitaxial Lateral Overgrowth of III‐Nitrides: Effects of Reactor Pressure in MOVPE Growth , 1999 .

[43]  Lutz Kirste,et al.  Growth and doping of semipolar GaN grown on patterned sapphire substrates , 2014 .

[44]  F. Scholz,et al.  Semipolar GaN grown on foreign substrates: a review , 2012 .

[45]  Michael Kunzer,et al.  Control of the mg doping profile in III-N light-emitting diodes and its effect on the electroluminescence efficiency , 2005 .

[46]  Umesh K. Mishra,et al.  Crystallographic orientation dependence of dopant and impurity incorporation in GaN films grown by metalorganic chemical vapor deposition , 2009 .