Applications of optically active metallacycles: new userful materials for the determination of the enantiomeric excess of Lewis bases and as resolving agents for monodentate phosphines

EnglishThe synthesis of new optically active cyclopalladated derivatives containing imines and primary amines is described as well as their applications for the determination of the enantiomeric excess and as resolving agents of Lewis bases. The synthesis and resolution of new monodentate P-chiral tertiary phosphines is also reported, as well as the application of these new ligands to asymmetric catalysis. Besides this, some chiral secondary phosphines have been prepared and their configurational stability has been studied catalaEs descriu la sintesi de nous compostos ciclopal·ladats derivats d'imines i amines primaries, opticament actius, aixi com les seves aplicacions per a la determinacio de l'exces enantiomeric i per a la resolucio de bases de Lewis. Tambe es comenta la sintesi i resolucio de noves fosfines P-quirals, aixi com la seva aplicacio a processos de catalisi asimetrica. A mes, es descriu la preparacio d'algunes fosfines secundaries quirals i s'estudia la seva estabilitat configuracional.

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