Chiral lutetium benzamidinate complexes.

Enantiomerically pure lutetium complexes were synthesized as the first rare earth metal complexes containing a chiral amidinate ligand. The catalytic activity and the enantioselectivity in hydroamination reactions were studied.

[1]  F. Edelmann Homogeneous Catalysis Using Lanthanide Amidinates and Guanidinates , 2011 .

[2]  Tianshu Li,et al.  Rare-Earth Metal Postmetallocene Catalysts with Chelating Amido Ligands , 2010 .

[3]  F. Edelmann Lanthanide amidinates and guanidinates: from laboratory curiosities to efficient homogeneous catalysts and precursors for rare-earth oxide thin films. , 2009, Chemical Society reviews.

[4]  T. Müller,et al.  Hydroamination: direct addition of amines to alkenes and alkynes. , 2008, Chemical reviews.

[5]  J. Collin,et al.  Asymmetric hydroamination of non-activated carbon-carbon multiple bonds. , 2007, Dalton transactions.

[6]  C. Wiemer,et al.  [(Me3Si)2N]3Lu: Molecular Structure and Use as Lu and Si Source for Atomic Layer Deposition of Lu Silicate Films , 2007 .

[7]  L. Weng,et al.  Synthesis and structural studies of some titanium and zirconium complexes with chiral bis(amide), amidinate or bis(amidinate) ligands , 2006 .

[8]  F. Hampel,et al.  Base-catalysed asymmetric hydroamination/cyclisation of aminoalkenes utilising a dimeric chiral diamidobinaphthyl dilithium salt. , 2006, Chemical communications.

[9]  P. Hitchcock,et al.  Racemic N-aryl bis(amidines) and bis(amidinates): on the trail of enantioselective organolanthanide catalysts. , 2006, Dalton transactions.

[10]  F. Hampel,et al.  3,3'-Bis(trisarylsilyl)-substituted binaphtholate rare earth metal catalysts for asymmetric hydroamination. , 2006, Journal of the American Chemical Society.

[11]  Andreas Bertogg A Novel Chiral Ferrocene-Based Amidine/Amidinato Ligand and Its Rhodium Complexes , 2006 .

[12]  M. Eisen,et al.  Synthesis, molecular structure and catalytic activity of chiral benzamidinate nickel complexes , 2005 .

[13]  M. Jung,et al.  gem-disubstituent effect: theoretical basis and synthetic applications. , 2005, Chemical reviews.

[14]  T. Livinghouse,et al.  Enantioselective intramolecular alkene hydroaminations catalyzed by yttrium complexes of axially chiral bis(thiolate) ligands. , 2005, Organic letters.

[15]  T. Marks,et al.  C2-symmetric bis(oxazolinato)lanthanide catalysts for enantioselective intramolecular hydroamination/cyclization. , 2003, Journal of the American Chemical Society.

[16]  Andreas Greiner,et al.  Unusual complex chemistry of rare-Earth elements: large ionic radii-small coordination numbers. , 2003, Angewandte Chemie.

[17]  W. Piers Non-cyclopentadienyl ancillaries in organogroup 3 metal chemistry: a fine balance in ligand design , 2002 .

[18]  F. Edelmann,et al.  Synthesis and structural chemistry of non-cyclopentadienyl organolanthanide complexes. , 2002, Chemical reviews.

[19]  L. Sita,et al.  Stereospecific Syntheses, Metal Configurational Stabilities, and Conformational Analyses of meso-(R,S)- and (R,R)-(η5-C5R5)Ti(CH3)2-N,N‘-bis(1-phenylethyl)acetamidinates for R = H and Me , 1999 .

[20]  M. Eisen,et al.  Stereoregular Polymerization of α-Olefins Catalyzed by Chiral Group 4 Benzamidinate Complexes of C1 and C3 Symmetry , 1998 .

[21]  T. Marks,et al.  Organolanthanide-catalyzed intramolecular hydroamination/cyclization of aminoalkynes , 1996 .

[22]  F. Edelmann Cyclopentadienyl‐Free Organolanthanide Chemistry , 1995 .

[23]  L. Esser,et al.  Synthesis, Structure, and Reactivity of Organometallic .pi.-Complexes of the Rare Earths in the Oxidation State Ln3+ with Aromatic Ligands , 1995 .

[24]  H. Brunner,et al.  Optisch aktive übergangsmetall-komplexe : LXVII. Konformationsanalyse der diastereomerengleichgewichte von quadratisch-pyramidalen C5H5(CO)2Mo-amidinato-komplexen , 1980 .

[25]  H. Brunner,et al.  Hydrierung prochiraler Olefine mit Rhodium-Komplexen von optisch aktiven Amidinen , 1980 .