Porous carbon nanofibers from electrospun polyacrylonitrile/SiO2 composites as an energy storage material

Abstract Porous carbon nanofibers with large accessible surface areas and well-developed pore structures were prepared by electrospinning and subsequent thermal and chemical treatments. They were directly used as anodes in lithium-ion batteries without adding any non-active materials such as polymer binders or electronic conductors. The electrochemical performance results show that porous carbon nanofiber anodes have improved lithium-ion storage ability, enhanced charge–discharge kinetics, and better cyclic stability compared with non-porous counterparts. The unique structures and properties of these materials make them excellent candidates for use as anodes in high-performance rechargeable lithium-ion batteries.

[1]  Shoji Yamaguchi,et al.  Interaction of Poly(vinylidene fluoride) with Graphite Particles. 2. Effect of Solvent Evaporation Kinetics and Chemical Properties of PVDF on the Surface Morphology of a Composite Film and Its Relation to Electrochemical Performance , 2004 .

[2]  Kunquan Hong,et al.  Diameter control of tungsten oxide nanowires as grown by thermal evaporation , 2008, Nanotechnology.

[3]  Jun Chen,et al.  Alpha-CuV2O6 nanowires: hydrothermal synthesis and primary lithium battery application. , 2008, Journal of the American Chemical Society.

[4]  Morinobu Endo,et al.  Self‐Sustained Thin Webs Consisting of Porous Carbon Nanofibers for Supercapacitors via the Electrospinning of Polyacrylonitrile Solutions Containing Zinc Chloride , 2007 .

[5]  Tao Zheng,et al.  Mechanisms for Lithium Insertion in Carbonaceous Materials , 1995, Science.

[6]  F. E. Little,et al.  Electrochemical performance of lithium ion battery, nano-silicon-based, disordered carbon composite anodes with different microstructures , 2004 .

[7]  Yan Yu,et al.  Electrospun carbon–cobalt composite nanofiber as an anode material for lithium ion batteries , 2008 .

[8]  R. Nesper,et al.  Synthesis and Characterization of Carbon‐Based Nanoparticles and Highly Magnetic Nanoparticles with Carbon Coatings , 2006 .

[9]  J. Dahn,et al.  Lithium Insertion in High Capacity Carbonaceous Materials , 1995 .

[10]  M. Armand,et al.  Issues and challenges facing rechargeable lithium batteries , 2001, Nature.

[11]  S. M. Lala,et al.  Carbon nanotube/felt composite electrodes without polymer binders , 2006 .

[12]  Yong Jung Kim,et al.  Fabrication of Electrospinning‐Derived Carbon Nanofiber Webs for the Anode Material of Lithium‐Ion Secondary Batteries , 2006 .

[13]  Dawei Zhang,et al.  Carbon nanofibers: Synthesis, characterization, and electrochemical properties , 2006 .

[14]  J. Santiago-Avilés,et al.  Raman characterization of carbon nanofibers prepared using electrospinning , 2003 .

[15]  Sudipta Seal,et al.  One dimensional nanostructured materials , 2007 .

[16]  M. Endo,et al.  A Mechanism of Lithium Storage in Disordered Carbons , 1994, Science.

[17]  Andreas Greiner,et al.  Electrospinning: a fascinating method for the preparation of ultrathin fibers. , 2007, Angewandte Chemie.

[18]  J. Dahn,et al.  Mechanism of lithium insertion in hard carbons prepared by pyrolysis of epoxy resins , 1996 .

[19]  Jeff Dahn,et al.  Lithium Insertion in Hydrogen-Containing Carbonaceous Materials , 1996 .

[20]  M. Wakihara Recent developments in lithium ion batteries , 2001 .

[21]  D. Reneker,et al.  Polybenzimidazole nanofiber produced by electrospinning , 1999 .

[22]  Jin-Song Hu,et al.  Nanostructured Materials for Electrochemical Energy Conversion and Storage Devices , 2008 .

[23]  Y. Xiong,et al.  Production of novel amorphous carbon nanostructures from ferrocene in low-temperature solution , 2004 .

[24]  B. Scrosati,et al.  Electronic and Electrochemical Properties of LixNi1-yCoyO2 Cathodes Studied by Impedance Spectroscopy , 2001 .

[25]  I. Alexandrou,et al.  Characterisation of carbon nano-onions using Raman spectroscopy , 2003 .

[26]  S. Ramakrishna,et al.  A review on electrospinning design and nanofibre assemblies , 2006, Nanotechnology.

[27]  M. Whittingham,et al.  Characterization of Amorphous and Crystalline Tin–Cobalt Anodes , 2007 .

[28]  Haoqing Hou,et al.  Electrospun Palladium Nanoparticle‐Loaded Carbon Nanofibers and Their Electrocatalytic Activities towards Hydrogen Peroxide and NADH , 2008 .

[29]  Park Tae Jin,et al.  Raman spectroscopic evaluation of polyacrylonitrile‐based carbon nanofibers prepared by electrospinning , 2004 .

[30]  Y. Kim,et al.  Synthesis and characterization of porous carbon nanofibers with hollow cores through the thermal treatment of electrospun copolymeric nanofiber webs. , 2007, Small.

[31]  Changwen Hu,et al.  One-step water-assisted synthesis of high-quality carbon nanotubes directly from graphite. , 2003, Journal of the American Chemical Society.

[32]  B. Tu,et al.  Ordered, Nanostructured Tin‐Based Oxides/Carbon Composite as the Negative‐Electrode Material for Lithium‐Ion Batteries , 2004 .

[33]  G. Cui,et al.  A Germanium–Carbon Nanocomposite Material for Lithium Batteries , 2008 .

[34]  P. Bruce,et al.  Nanostructured materials for advanced energy conversion and storage devices , 2005, Nature materials.

[35]  P. Bruce,et al.  Nanomaterials for rechargeable lithium batteries. , 2008, Angewandte Chemie.

[36]  M. Márquez,et al.  Filled and Hollow Carbon Nanofibers by Coaxial Electrospinning of Alcell Lignin without Binder Polymers , 2007 .

[37]  I. Honma,et al.  Lithium Storage in Ordered Mesoporous Carbon (CMK‐3) with High Reversible Specific Energy Capacity and Good Cycling Performance , 2003 .

[38]  Xiangwu Zhang,et al.  Preparation and characterization of silica nanoparticulate–polyacrylonitrile composite and porous nanofibers , 2008, Nanotechnology.

[39]  J. Jang,et al.  Polyacrylonitrile Nanofibers: Formation Mechanism and Applications as a Photoluminescent Material and Carbon‐Nanofiber Precursor , 2006 .

[40]  David G Simpson,et al.  Electrospinning of collagen nanofibers. , 2002, Biomacromolecules.

[41]  H. Dai,et al.  Self-oriented regular arrays of carbon nanotubes and their field emission properties , 1999, Science.

[42]  Petr Novák,et al.  Insertion Electrode Materials for Rechargeable Lithium Batteries , 1998 .

[43]  Younan Xia,et al.  Electrospinning of Nanofibers: Reinventing the Wheel? , 2004 .

[44]  L. Kavan,et al.  Li Insertion into Li4Ti5 O 12 (Spinel) Charge Capability vs. Particle Size in Thin-Film Electrodes , 2003 .