Development of High Performance Ceria/Bismuth Oxide Bilayered Electrolyte SOFCs for Lower Temperature Operation

This study examines the development of lower temperature solid oxide fuel cells (SOFCs) and the incremental improvement in performance obtained from a wide range of techniques, from pressed anodes to tape-cast anodes, from gadolinia-doped ceria (GDC) single-layer electrolytes to erbium-stabilized bismuth oxide (ESB)/GDC bilayer, and from La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ -GDC composite cathodes to optimized Bi 2 Ru 2 O 7 -ESB composites. GDC single-layer electrolyte-based SOFCs were prepared from four different fabrications and exhibit maximum power densities ranging from 0.338 to 1.03 W/cm 2 at 650°C. At each fabrication stage, an ESB layer was applied to form a bilayer electrolyte. ESB was deposited by a range of techniques including colloidal deposition and pulsed laser deposition. The result confirms that depending on a fabrication route, the bilayer electrolyte can reduce the total area specific resistance (ASR) 33-49% and increase the maximum power density 44-93%. By using a combination of the materials and fabrication routes, a maximum power density of 1.95 W/cm 2 and 0.079 Ω cm 2 total cell ASR was achieved at 650°C for a bilayer cell.