New thiophene metallacarbaborane compounds of palladium and platinum: X-ray structures of 1-C4H3S-3-(cod)-3,1,2-M-C2B9H10, 1-C4H3S-3,3-(PMe2Ph)2-3,1,2-Pt–C2B9H10 and 1-C4H3S-3,3-(PPh2CH2CH2Ph2)-3,1,2-Pd-C2B9H10 (M=Pt or Pd)