Influence of Meso and Nanoscale Structure on the Properties of Highly Efficient Small Molecule Solar Cells

The nanoscale morphology of the bulk heterojunction absorber layer in an organic solar cell (OSC) is of key importance for its efficiency. The morphology of high performance vacuum-processed, small molecule OSCs based on oligothiophene derivatives (DCV5T-Me) blended with C60 on various length scales is studied. The analytical electron microscopic techniques such as scanning transmission electron microscopy, energy dispersive X-ray spectroscopy, highly sensitive external quantum efficiency measurements, and meso and nanoscale simulations are employed. Unique insights into the relation between processing, morphology, and efficiency of the final devices are obtained. It is shown that the connectivity of the oligothiophene-C60 network is independent of the material domain size. The decisive quantity controlling the internal quantum efficiency is the energetic disorder induced by material mixing, strongly limiting charge and exciton transport in the OSCs.

[1]  S. C. O'brien,et al.  C60: Buckminsterfullerene , 1985, Nature.

[2]  Martin Pfeiffer,et al.  Optimizing organic photovoltaics using tailored heterojunctions: A photoinduced absorption study of oligothiophenes with low band gaps , 2008 .

[3]  James H. Bannock,et al.  Direct Correlation of Charge Transfer Absorption with Molecular Donor:Acceptor Interfacial Area via Photothermal Deflection Spectroscopy. , 2015, Journal of the American Chemical Society.

[4]  Stephen R Forrest,et al.  Relationship between Crystalline Order and Exciton Diffusion Length in Molecular Organic Semiconductors , 2010, Advanced materials.

[5]  G. Ozin,et al.  looking inside a working SiLED. , 2013, Nano letters.

[6]  K. Leo,et al.  Organic thin film photovoltaic cells based on planar and mixed heterojunctions between fullerene and a low bandgap oligothiophene , 2009 .

[7]  Andreas Henemann,et al.  BIPV: Built-in solar energy , 2008 .

[8]  C. Tang Two‐layer organic photovoltaic cell , 1986 .

[9]  Hiroshi Fujiwara,et al.  Three‐layered organic solar cell with a photoactive interlayer of codeposited pigments , 1991 .

[10]  Hans W. Horn,et al.  ELECTRONIC STRUCTURE CALCULATIONS ON WORKSTATION COMPUTERS: THE PROGRAM SYSTEM TURBOMOLE , 1989 .

[11]  D. McComb,et al.  Uncovering Buried Structure and Interfaces in Molecular Photovoltaics , 2014 .

[12]  John R. Tumbleston,et al.  Domain Purity, Miscibility, and Molecular Orientation at Donor/Acceptor Interfaces in High Performance Organic Solar Cells: Paths to Further Improvement , 2013 .

[13]  P. Guttmann,et al.  Investigating local (photo-)current and structure of ZnPc:C60 bulk-heterojunctions , 2013 .

[14]  Pascal Friederich,et al.  Generalized effective-medium model for the carrier mobility in amorphous organic semiconductors , 2015 .

[15]  Karl Leo,et al.  Impact of mesoscale order on open-circuit voltage in organic solar cells. , 2015, Nature materials.

[16]  Peter Peumans,et al.  Effect of molecular packing on the exciton diffusion length in organic solar cells , 2007 .

[17]  F. Hamprecht,et al.  Visualizing a homogeneous blend in bulk heterojunction polymer solar cells by analytical electron microscopy. , 2011, Nano letters.

[18]  Youjin Deng,et al.  Bond and site percolation in three dimensions. , 2013, Physical review. E, Statistical, nonlinear, and soft matter physics.

[19]  Pascal Friederich,et al.  QM/QM approach to model energy disorder in amorphous organic semiconductors. , 2015, Journal of chemical theory and computation.

[20]  M. Weil,et al.  Dicyanovinyl–Substituted Oligothiophenes: Structure‐Property Relationships and Application in Vacuum‐Processed Small Molecule Organic Solar Cells , 2011 .

[21]  Pascal Friederich,et al.  Ab Initio Treatment of Disorder Effects in Amorphous Organic Materials: Toward Parameter Free Materials Simulation. , 2014, Journal of chemical theory and computation.

[22]  Stephen R. Forrest,et al.  Small molecular weight organic thin-film photodetectors and solar cells , 2003 .

[23]  Fei Huang,et al.  Small-molecule solar cells with efficiency over 9% , 2014, Nature Photonics.

[24]  K. Leo,et al.  Increase in internal quantum efficiency in small molecular oligothiophene: C60 mixed heterojunction solar cells by substrate heating , 2010 .

[25]  Wei Chen,et al.  Visualization of Hierarchical Nanodomains in Polymer/Fullerene Bulk Heterojunction Solar Cells , 2014, Microscopy and Microanalysis.

[26]  Martin Pfeiffer,et al.  Organic p-i-n solar cells , 2004 .

[27]  A. Walker,et al.  Dynamical Monte Carlo modelling of organic solar cells: the dependence of internal quantum efficiency on morphology. , 2005, Nano letters.

[28]  K. Leo,et al.  Increase of charge carrier lifetime in dicyanovinyl–quinquethiophene: fullerene blends upon deposition on heated substrates , 2011 .

[29]  M. Toney,et al.  Probing the effect of substrate heating during deposition of DCV4T:C60 blend layers for organic solar cells , 2012 .

[30]  K. Malarz Simple cubic random-site percolation thresholds for neighborhoods containing fourth-nearest neighbors. , 2014, Physical review. E, Statistical, nonlinear, and soft matter physics.

[31]  Stephen J. Pennycook,et al.  Z-contrast stem for materials science , 1989 .

[32]  K. Leo,et al.  Highly efficient organic multi-junction solar cells with a thiophene based donor material , 2014 .

[33]  Martin Pfeiffer,et al.  Efficient Vacuum‐Deposited Organic Solar Cells Based on a New Low‐Bandgap Oligothiophene and Fullerene C60 , 2006 .

[34]  J. Hummelen,et al.  Polymer Photovoltaic Cells: Enhanced Efficiencies via a Network of Internal Donor-Acceptor Heterojunctions , 1995, Science.

[35]  Wolfgang Wenzel,et al.  Modeling disordered morphologies in organic semiconductors , 2013, J. Comput. Chem..

[36]  Jean-Luc Brédas,et al.  Charge transport in organic semiconductors. , 2007, Chemical reviews.

[37]  D. Huber Diffusion of optical excitation at finite temperatures , 1983 .

[38]  H. Bässler Charge Transport in Disordered Organic Photoconductors a Monte Carlo Simulation Study , 1993 .

[39]  Matthias Weil,et al.  Correlation of π-conjugated oligomer structure with film morphology and organic solar cell performance. , 2012, Journal of the American Chemical Society.

[40]  V. Nicolosi,et al.  Gentle STEM: ADF imaging and EELS at low primary energies $ , 2010 .

[41]  P. Bäuerle,et al.  Orbital redistribution in molecular nanostructures mediated by metal-organic bonds. , 2014, ACS nano.

[42]  David B. Williams,et al.  Transmission Electron Microscopy , 1996 .

[43]  M. Malac,et al.  Radiation damage in the TEM and SEM. , 2004, Micron.

[45]  Wei You,et al.  The influence of molecular orientation on organic bulk heterojunction solar cells , 2014, Nature Photonics.