Assessing quantification for the EMS algorithm

Abstract A framework is developed for assessing the potential of the EMS (estimate, maximize, and smooth) algorithm to correctly quantify the emission it aims to reconstruct. Maximal eigenvector localization bounds of Perron-Frobenius theory are used to show that the ability of the EMS algorithm to quantify differences in emission is fundamentally limited by the smoothing imposed and the properties of the underlying model matrix in the algorithm. In particular, it is established that, for nonnegative irreducible smoothing, the EMS algorithm will always fail to correctly reconstruct zero emission intensity.

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