Novel Scalable Transfer Approach for Discrete III‐Nitride Devices Using Wafer‐Scale Patterned h‐BN/Sapphire Substrate for Pick‐and‐Place Applications

The mechanical release of III‐nitride devices using h‐BN is a promising approach for heterogeneous integration. Upscaling this technology for industrial level requires solutions that allow a simple pick‐and‐place technique of selected devices for integration while preserving device performance. An advance that satisfies both of these requirements is demonstrated in this work. It is based on a lateral control of the h‐BN quality, using patterned sapphire with a SiO2 mask, to achieve localized van der Waals epitaxy of high‐quality GaN based device structures. After process fabrication, the devices can be individually picked and placed on a foreign substrate without the need for a dicing step. In addition, this approach could reduce delamination of h‐BN on large diameter substrates because each h‐BN region is smaller, with independent device structures. Discrete InGaN LEDs on h‐BN are grown and fabricated on 2 in. patterned sapphire using a SiO2 mask. A set of devices are selectively released and transferred to flexible aluminum tape. The transferred LEDs exhibit blue light emission around 435 nm. The approach presented here is scalable on any wafer size, can be applied to other types of nitride‐based devices, and can be compatible with commercial pick‐and‐place handlers for mass production.

[1]  C. Jagadish,et al.  Flow modulation epitaxy of hexagonal boron nitride , 2018, 2D Materials.

[2]  Structural and compositional characterization of MOVPE GaN thin films transferred from sapphire to glass substrates using chemical lift-off and room temperature direct wafer bonding and GaN wafer scale MOVPE growth on ZnO-buffered sapphire , 2013 .

[3]  James J.-Q. Lu,et al.  Solid-state neutron detectors based on thickness scalable hexagonal boron nitride , 2016, 1610.03053.

[4]  Xin Li,et al.  Large-Area Two-Dimensional Layered Hexagonal Boron Nitride Grown on Sapphire by Metalorganic Vapor Phase Epitaxy , 2016 .

[5]  K. Kumakura,et al.  Layered boron nitride as a release layer for mechanical transfer of GaN-based devices , 2012, Nature.

[6]  Xin Li,et al.  Heterogeneous Integration of Thin-Film InGaN-Based Solar Cells on Foreign Substrates with Enhanced Performance , 2018, ACS Photonics.

[7]  Oliver Ambacher,et al.  Large Free-Standing GaN Substrates by Hydride Vapor Phase Epitaxy and Laser-Induced Liftoff , 1999 .

[8]  Dong Liu,et al.  Transfer print techniques for heterogeneous integration of photonic components , 2017 .

[9]  Yei Hwan Jung,et al.  Releasable High‐Performance GaAs Schottky Diodes for Gigahertz Operation of Flexible Bridge Rectifier , 2018, Advanced Electronic Materials.

[10]  C. Dimitrakopoulos,et al.  Principle of direct van der Waals epitaxy of single-crystalline films on epitaxial graphene , 2014, Nature Communications.

[11]  Abdallah Ougazzaden,et al.  Wafer-scale controlled exfoliation of metal organic vapor phase epitaxy grown InGaN/GaN multi quantum well structures using low-tack two-dimensional layered h-BN , 2016 .

[12]  D. Bhattacharyya,et al.  Graphene-based materials and their composites: A review on production, applications and product limitations , 2018, Composites Part B: Engineering.

[13]  Y. S. Wu,et al.  Laser Lift-Off Mechanisms of GaN Epi-Layer Grown on Pattern Sapphire Substrate , 2015 .

[14]  Xin Li,et al.  Gas sensors boosted by two-dimensional h-BN enabled transfer on thin substrate foils: towards wearable and portable applications , 2017, Scientific Reports.

[15]  M. Razeghi,et al.  Chemical lift-off and direct wafer bonding of GaN/InGaN P-I-N structures grown on ZnO , 2016 .