Targeting of the Water-Energy Nexus in Gas-to-Liquid Processes: A Comparison of Syngas Technologies

The abundant supply of natural gas and the increasing reserves due to substantial shale gas discoveries are spurring much interest in gas-to-liquid (GTL) technologies that can provide various liquid transportation fuels. A primary GTL route involves the conversion of natural/shale gas to syngas which is subsequently converted to liquid fuels using the Fischer–Tropsch (FT) chemistry. The FT process is both energy and water intensive and has resulted in substantial efforts aimed at improving the design and operation of large-scale GTL facilities within the context of sustainability. Although the process technologies have been proven commercially, little is known about the heuristics involved in the selection, design, and operation of certain core process units. In specific, the choice of syngas production technology has been heavily debated based on various factors such as cost, hydrogen-to-carbon monoxide ratio, compatibility with the rest of the process through mass and energy integration, environmental i...

[1]  M. El‐Halwagi,et al.  Optimization and Selection of Reforming Approaches for Syngas Generation from Natural/Shale Gas , 2014 .

[2]  A. Jiménez-Gutiérrez,et al.  Water and energy issues in gas-to-liquid processes: Assessment and integration of different gas-reforming alternatives , 2014 .

[3]  Chikezie Nwaoha,et al.  Gas-to-liquids (GTL): A review of an industry offering several routes for monetizing natural gas , 2012 .

[4]  Magne Hillestad,et al.  Techno‐Economic Analysis of a Gas‐to‐Liquid Process with Different Placements of a CO2 Removal Unit , 2012 .

[5]  Arno de Klerk,et al.  Fischer-Tropsch Refining: DE KLERK:FISCHER-TROPSCH O-BK , 2011 .

[6]  L. Pellegrini,et al.  Liquid fuels from Fischer–Tropsch wax hydrocracking: Isomer distribution , 2010 .

[7]  M. El‐Halwagi,et al.  Simulation, integration, and economic analysis of gas-to-liquid processes , 2010 .

[8]  Kyoung‐Su Ha,et al.  Efficient utilization of greenhouse gas in a gas-to-liquids process combined with carbon dioxide reforming of methane. , 2010, Environmental science & technology.

[9]  Mahmoud M. El-Halwagi,et al.  Targeting cogeneration and waste utilization through process integration , 2009 .

[10]  R. Zennaro,et al.  Gas to liquids technologies for natural gas reserves valorization: The Eni experience , 2009 .

[11]  S. H. Kim,et al.  Hydrogen separation by multi-bed pressure swing adsorption of synthesis gas , 2008 .

[12]  E. Steen,et al.  Fischer‐Tropsch Catalysts for the Biomass‐to‐Liquid (BTL)‐Process , 2008 .

[13]  T. Nenoff,et al.  Membranes for hydrogen separation. , 2007, Chemical reviews.

[14]  S. Basu,et al.  Gas-to-liquid technologies: India's perspective , 2007 .

[15]  D. Leckel Noble Metal Wax Hydrocracking Catalysts Supported on High-Siliceous Alumina , 2007 .

[16]  F. G. Botes,et al.  Proposal of a new product characterization model for the iron-based low-temperature Fischer-Tropsch synthesis , 2007 .

[17]  D. Leckel Selectivity Effect of Oxygenates in Hydrocracking of Fischer−Tropsch Waxes , 2007 .

[18]  D. Leckel,et al.  Diesel-Selective Hydrocracking of an Iron-Based Fischer−Tropsch Wax Fraction (C15−C45) Using a MoO3-Modified Noble Metal Catalyst , 2006 .

[19]  J. Niemantsverdriet,et al.  XANES study of the susceptibility of nano-sized cobalt crystallites to oxidation during realistic Fischer–Tropsch synthesis , 2006 .

[20]  A. Ophir,et al.  Advanced MED process for most economical sea water desalination , 2005 .

[21]  K. Hall A new gas to liquids (GTL) or gas to ethylene (GTE) technology , 2005 .

[22]  L. Pellegrini,et al.  Hydroconversion of Fischer–Tropsch waxes: Assessment of the operating conditions effect by factorial design experiments , 2005 .

[23]  Mahmoud M. El-Halwagi,et al.  Simultaneous synthesis of waste interception and material reuse networks: Problem reformulation for global optimization , 2005 .

[24]  J. Ancheyta,et al.  Kinetic Model for Moderate Hydrocracking of Heavy Oils , 2005 .

[25]  I. Puskas,et al.  Comments about the causes of deviations from the Anderson–Schulz–Flory distribution of the Fischer–Tropsch reaction products , 2003 .

[26]  Mahmoud M. El-Halwagi,et al.  RIGOROUS GRAPHICAL TARGETING FOR RESOURCE CONSERVATION VIA MATERIAL RECYCLE/REUSE NETWORKS , 2003 .

[27]  G. V. D. Laan,et al.  Kinetics and Selectivity of the Fischer–Tropsch Synthesis: A Literature Review , 1999 .

[28]  B. Jager,et al.  Advances in low temperature Fischer-Tropsch synthesis , 1995 .

[29]  M. Dry High quality diesel via the Fischer–Tropsch process – a review , 2002 .

[30]  J. H. Wilson,et al.  Non-ASF product distributions due to secondary reactions during Fischer-Tropsch synthesis , 1996 .