By applying the Adams-Bashforth-Moulton method (ABM), this paper explores the complexity and synchronization of a fractional-order laser dynamical model. The dynamics under the variance of derivative order q and parameters of the system have examined using the multiscale complexity algorithm and the bifurcation diagram. Numerical simulation outcomes demonstrate that the system generates chaos with the decreasing of q. Moreover, this paper designs the coupled fractional-order network of laser systems and subsequently obtains its numerical solution using ABM. These solutions have demonstrated chimera states of the proposed fractional-order laser network.