Detection of Type, Blended Ratio, and Mixed Ratio of Pu’er Tea by Using Electronic Nose and Visible/Near Infrared Spectrometer

The objective of this study was to find an intelligent and fast method to detect the type, blended ratio, and mixed ratio of ancient Pu’er tea, which is significant in maintaining order in the Pu’er tea industry. An electronic nose (E-nose) and a visible near infrared spectrometer (VIS/NIR spectrometer) were applied for tea sampling. Feature extraction was conducted using both the traditional method and a convolutional neural network (CNN) technique. Linear discriminant analysis (LDA) and partial least square regression (PLSR) were applied for pattern recognition. After sampling while using the traditional method, the analysis of variance (ANOVA) results showed that the mean differential value of each sensor should be selected as the optimal feature extraction method for E-nose data, and raw data comparison results showed that 19 peak/valley values and two slope values were extracted. While the format of E-nose data was in accord with the input format for CNN, the VIS/NIR spectrometer data required matrixing to meet the format requirements. The LDA and PLSR analysis results showed that CNN has superior detection ability, being able to acquire more local features than the traditional method, but it has the risk of mixing in redundant information, which can act to reduce the detection ability. Multi-source information fusion (E-nose and VIS/NIR spectrometer fusion) can collect more features from different angles to improve the detection ability, but it also contains the risk of adding redundant information, which reduces the detection ability. For practical detection, the type of Pu’er tea should be recognizable using a VIS/NIR spectrometer and the traditional feature extraction method. The blended ratio of Pu’er tea should also be identifiable by using a VIS/NIR spectrometer with traditional feature extraction. Multi-source information fusion with traditional feature extraction should be used if the accuracy requirement is extremely high; otherwise, a VIS/NIR spectrometer with traditional feature extraction is preferred.

[1]  Huichao Jiang,et al.  [Genetic diversity of ancient tea gardens and tableland tea gardens from Yunnan Province as revealed by AFLP marker]. , 2009, Yi chuan = Hereditas.

[2]  Dong Guangjun,et al.  The Processing of Information Fusion Based on Rough Set Theory , 2005 .

[3]  Haixia Chen,et al.  Physicochemical properties and antioxidant capacity of 3 polysaccharides from green tea, oolong tea, and black tea. , 2009, Journal of food science.

[4]  Yuerong Liang,et al.  A study on chemical estimation of pu-erh tea quality , 2005 .

[5]  Yuerong Liang,et al.  Processing and chemical constituents of Pu-erh tea: A review , 2013 .

[6]  Wei Wang,et al.  Discriminant research for identifying aromas of non‐fermented Pu‐erh tea from different storage years using an electronic nose , 2018, Journal of Food Processing and Preservation.

[7]  M. Yılmaz,et al.  A rapid ATR-FTIR spectroscopic method for detection of sibutramine adulteration in tea and coffee based on hierarchical cluster and principal component analyses. , 2017, Food chemistry.

[8]  Andrey S. Krylov,et al.  No-Reference Stereoscopic Image Quality Assessment Using Convolutional Neural Network for Adaptive Feature Extraction , 2018, IEEE Access.

[9]  Xiuping Jia,et al.  Deep Feature Extraction and Classification of Hyperspectral Images Based on Convolutional Neural Networks , 2016, IEEE Transactions on Geoscience and Remote Sensing.

[10]  David H. Vaughan,et al.  Non-destructive evaluation of apple maturity using an electronic nose system , 2006 .

[11]  Stanislaw Osowski,et al.  Recognition of Coffee Using Differential Electronic Nose , 2012, IEEE Transactions on Instrumentation and Measurement.

[12]  Jun Wang,et al.  Discrimination of LongJing green-tea grade by electronic nose , 2007 .

[13]  Feng Chen,et al.  Evaluation of the synergism among volatile compounds in Oolong tea infusion by odour threshold with sensory analysis and E-nose. , 2017, Food chemistry.

[14]  Stijn Lichtert,et al.  Statistical consequences of applying a PCA noise filter on EELS spectrum images. , 2013, Ultramicroscopy.

[15]  Z. Jun,et al.  Genetic diversity of ancient tea gardens and tableland tea gardens from Yunnan Province as revealed by AFLP marker , 2009 .

[16]  An Wen-jie Changes of Chemical Components in Pu'er Tea Produced by Solid State Fermentation of Sundried Green Tea , 2005 .

[17]  Tahir Mehmood,et al.  A review of variable selection methods in Partial Least Squares Regression , 2012 .

[18]  Baijuan Wang,et al.  Discrimination of Unfermented Pu’er Tea Aroma of Different Years Based on Electronic Nose , 2017, Agricultural Research.

[19]  Wang Xiao-li Detection for rice odors and identification of varieties based on electronic nose technique , 2011 .

[20]  Abbes Amira,et al.  An Empirical Study for PCA- and LDA-Based Feature Reduction for Gas Identification , 2016, IEEE Sensors Journal.

[21]  K. Triyana,et al.  Detecting aroma changes of local flavored green tea (Camellia sinensis) using electronic nose , 2018 .

[22]  Thomas Hueber,et al.  Feature extraction using multimodal convolutional neural networks for visual speech recognition , 2017, 2017 IEEE International Conference on Acoustics, Speech and Signal Processing (ICASSP).

[23]  Pai Peng,et al.  Gas Classification Using Deep Convolutional Neural Networks , 2018, Sensors.

[24]  Genetic diversity and relationship of tea germplasm in Yunnan revealed by ISSR analysis. , 2010 .

[25]  Jiewen Zhao,et al.  Intelligent evaluation of color sensory quality of black tea by visible-near infrared spectroscopy technology: A comparison of spectra and color data information. , 2017, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[26]  Tao Liu,et al.  Multi-source information fusion applied to structural damage diagnosis , 2011 .

[27]  Yong He,et al.  [Application PCA-ANN method to fast discrimination of tea varieties using visible/near infrared spectroscopy]. , 2007, Guang pu xue yu guang pu fen xi = Guang pu.