An Electrolysis-Bubble-Actuated Micropump Based on the Roughness Gradient Design of Hydrophobic Surface

A novel electrolysis-bubble-actuated micropump based on the roughness gradient design in the microchannel is reported in this paper. This micropump is implemented by taking advantage of both the electrolysis actuation and the surface tension effect. The surface tension effect is controlled via the periodic generation of electrolytic bubbles and the roughness gradient design of microchannel surface, which results in the specified variation of liquid contact angle along the microchannel. Our proposed micropump could resolve the disadvantages that exist in the early reported micropumps, such as the complicated time-sequence power control, the need of long nozzle-diffuser structure, and the choking/sticking phenomena of electrolytic bubbles in a microchannel. Due to the features of large actuation force, low-power consumption, and room temperature operation, our micropump is suitable for the development of low-power consumption and compact micropumps for various applications. Experimental results show that the liquid displacement and the pumping rate could be easily and accurately controlled by adjusting the amplitude and frequency of the applied voltage. With the applied voltage of 15 V at 4.5 Hz, a maximum pumping rate of 114 nl/min is achieved for one of our micropump designs with a microchannel of 100 x 20 mum. In this paper, we report the theoretical analysis, design, micromachining process, operating principles, characterization, and experimental demonstration of these micropumps.

[1]  Contact Angle Hysteresis Characterization of Textured Super-Hydrophobic Surfaces , 2007, TRANSDUCERS 2007 - 2007 International Solid-State Sensors, Actuators and Microsystems Conference.

[2]  Lichao Gao,et al.  "Artificial lotus leaf" prepared using a 1945 patent and a commercial textile. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[3]  K. Böhringer,et al.  Directing droplets using microstructured surfaces. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[4]  K. Böhringer,et al.  BOUNDS ON CONTACT ANGLE HYSTERESIS OF TEXTURED SUPER-HYDROPHOBIC SURFACES , 2006 .

[5]  Chang-Jin Kim,et al.  Micropumping by directional growth and hydrophobic venting of bubbles , 2005, 18th IEEE International Conference on Micro Electro Mechanical Systems, 2005. MEMS 2005..

[6]  K. Bohringer,et al.  Engineering surface roughness to manipulate droplets in microfluidic systems , 2005, 18th IEEE International Conference on Micro Electro Mechanical Systems, 2005. MEMS 2005..

[7]  Neelesh A. Patankar,et al.  A roughness-based wettability switching membrane device for hydrophobic surfaces , 2005 .

[8]  Andrea Prosperetti,et al.  A microfluidic ‘blinking bubble’ pump , 2005 .

[9]  Glen McHale,et al.  The use of high aspect ratio photoresist (SU-8) for super-hydrophobic pattern prototyping , 2004 .

[10]  J. Santiago,et al.  A review of micropumps , 2004 .

[11]  Susan Z. Hua,et al.  An electrolytically actuated micropump , 2004 .

[12]  Chih-Ming Ho,et al.  A MEMBRANE BREATHER FOR MICRO FUEL CELL WITH HIGH CONCENTRATION METHANOL , 2004 .

[13]  Jay D. Keasling,et al.  A microfabricated electrochemical oxygen generator for high-density cell culture arrays , 2003 .

[14]  Michael S. Freund,et al.  Reversible and efficient materials-based actuation by electrolytic phase transformation , 2003 .

[15]  D. J. Harrison,et al.  Microfabricated electrolysis pump system for isolating rare cells in blood , 2003 .

[16]  Liwei Lin,et al.  A thermal-bubble-actuated micronozzle-diffuser pump , 2002 .

[17]  Christopher D. Batich,et al.  Fabrication and testing of a magnetically actuated micropump , 2002 .

[18]  Il-Joo Cho,et al.  A surface-tension driven micropump for low-voltage and low-power operations , 2002 .

[19]  Liwei Lin,et al.  Transient Thermal Bubble Formation on Polysilicon Micro-Resisters , 2002 .

[20]  C. Kim,et al.  Electrowetting and electrowetting-on-dielectric for microscale liquid handling , 2002 .

[21]  Dennis L. Polla,et al.  Design and simulation of an implantable medical drug delivery system using microelectromechanical systems technology , 2001 .

[22]  Andrea Prosperetti,et al.  Bubble-based micropump for electrically conducting liquids , 2001 .

[23]  A. Pisano,et al.  Characterization of a Micro-Mixing, Pumping, and Valving System , 2001 .

[24]  Peter Enoksson,et al.  A Valve-Less Diffuser Micropump for Microfluidic Analytical Systems , 2001 .

[25]  Wouter Olthuis,et al.  A closed-loop controlled electrochemically actuated micro-dosing system , 2000 .

[26]  O. Jeong,et al.  Fabrication and test of a thermopneumatic micropump with a corrugated p+ diaphragm , 2000 .

[27]  G. Whitesides,et al.  Patterning electro-osmotic flow with patterned surface charge. , 2000, Physical review letters.

[28]  J. Bico,et al.  Pearl drops , 1999 .

[29]  P. Bergveld,et al.  An Integrated Micromachined Electrochemical Pump and Dosing System , 1999, Biomedical microdevices.

[30]  Carlos H. Mastrangelo,et al.  MICROFABRICATED PLASTIC CAPILLARY SYSTEMS WITH PHOTO-DEFINABLE HYDROPHILIC AND HYDROPHOBIC REGIONS , 1999 .

[31]  Chang-JinCJ Kim,et al.  Valveless pumping using traversing vapor bubbles in microchannels , 1998 .

[32]  Olivier Français,et al.  Dynamic simulation of an electrostatic micropump with pull-in and hysteresis phenomena , 1998 .

[33]  M. Burns,et al.  Microfabricated capillarity-driven stop valve and sample injector , 1998, Proceedings MEMS 98. IEEE. Eleventh Annual International Workshop on Micro Electro Mechanical Systems. An Investigation of Micro Structures, Sensors, Actuators, Machines and Systems (Cat. No.98CH36176.

[34]  Neil M. White,et al.  A novel micromachined pump based on thick-film piezoelectric actuation , 1997, Proceedings of International Solid State Sensors and Actuators Conference (Transducers '97).

[35]  Tomohiro Onda,et al.  Super Water-Repellent Surfaces Resulting from Fractal Structure , 1996 .

[36]  D. J. Harrison,et al.  Electroosmotic pumping and electrophoretic separations for miniaturized chemical analysis systems , 1994 .

[37]  Klaus Hofmann,et al.  A micromachined electrohydrodynamic (EHD) pump , 1991 .

[38]  J. Hoare Some effects of alternating current polarization on the surface of noble metal electrodes , 1964 .

[39]  J. J. Bikerman,et al.  The Surface Roughness and Contact Angle. , 1950 .

[40]  A. Cassie,et al.  Wettability of porous surfaces , 1944 .