Hybrid Perovskites ; New Opportunities beyond Oxides

│Current studies on hybrid organic-inorganic perovskites (HOIPs) are predominantly focused on hybrid halides for photovoltaic and optoelectronic properties. However, the field of HOIPs is a much broader one that encompasses other important families, such as formates, azides, dicyanamides, cyanides and dicyanometallates. These HOIP materials have several common features, including not only the ABX3 structural architecture but also the presence of organic ammonium cations and their associated physical properties. These features lead to some remarkable behaviour, especially in the domain of phase transitions. In this review, we summarise the recent advances in the synthesis, structures and physical properties of all HOIP classes and discuss future opportunities in this exciting area. The word perovskite was coined to name the calcium titanium oxide mineral, CaTiO3, which was discovered in the Ural Mountains of Russia by the German mineralogist Gustav Rose and named in honour of the Russian Count, Lev A. Perovski. Nowadays, perovskite refers to a broad class of materials which have the same type of structure as CaTiO3, known as the perovskite structure. The general chemical formula

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