论文信息 - Selective complexation of disaccharides by a novel D2-symmetrical receptor in protic solvent mixtures

Selective complexation of disaccharides by a novel D2-symmetrical receptor in protic solvent mixtures

The synthesis of an optically active, 1,1′-binaphtyl-derived cyclophane receptor with a preorganized central cavity lined with four anionic phosphodiester groups for ionic hydrogen bonding is described. In competitive protic solvent mixtures, this receptor forms stable 1:1 complexes with disaccharides whereas the smaller monosaccharides are not significantly bound.

F. Diederich | Ulf Neidlein

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