Absorption by dissolved organic matter of the sea (yellow substance) in the UV and visible domains1

Spectral values of absorption of light by dissolved organic matter were measured in samples originating from diverse parts of the ocean, quite different with respect to pigment and particle content. The use of llO-cm cells and then of lo-cm cells, with a highly sensitive spectrophotometer, allowed measurement throughout the UV-visible range (200-700 nm) even for the low concentrations of yellow substance encountered in the open sea. The concentration appears influenced predominantly by natural and industrial land discharges. In oceanic waters, it remains low and seems to be related to the biological activity averaged over a long period rather than to the local and temporary phytoplankton content. However, even at such low concentrations, yellow substance in the open sea may have an effect on absorption and hence on ocean color similar to that of low or moderate algal biomass. The spectral dependence law of absorption appears to vary within a restricted range, and an average law can be considered representative of rapid measurements at one selected wavelength.