Effect of Ag Alloying on Microstructure, Mechanical and Electrical Properties of NiAl Intermetallic Compound

In this paper, the effects of Ag on microstructure, mechanical and electrical properties of NiAl intermetallic compound were investigated. The present results show that the NiAl-Ag alloys consisted of two phases: beta-NiAl and Ag-rich solid solution. The amount of the Ag-rich phase increased with increasing Ag content. Ag has very low solubility in NiAl and they form pseudo-binary monotectic systems. The addition of 0.5-1at.% Ag to NiAl increased its strength while the addition of more than 1at.% Ag decreased its strength. The strengthening and weakening effects come from solid solution hardening and second ductile phase softening. In addition, Ag alloying can improve NiAl's room temperature compressive ductility. The NiAl-Ag alloy has high hardness and electrical conductivity that make it an attractive candidate for electrical contact material. (C) 2003 Elsevier Science B.V. All rights reserved.

[1]  Dian‐sen Li,et al.  Preliminary investigation of directionally solidified NiAl–28Cr–5.5Mo–0.5Hf composite , 2000 .

[2]  Douxing Li,et al.  Substitution behavior in NiAl -- A first principle prediction considering lattice relaxation , 1998 .

[3]  Z. Horita,et al.  Microstructure and strength of B2-ordered NiAl containing L21-Ni2AlHf precipitates , 1997 .

[4]  R. Noebe,et al.  Elevated temperature compressive properties of Zr-modified NiAl , 1996 .

[5]  J. Verhoeven,et al.  Deformation-processed copper-chromium alloys: Role of age hardening , 1995, Journal of Materials Engineering and Performance.

[6]  J. Verhoeven,et al.  Deformation-processed copper-chromium alloys: Optimizing strength and conductivity , 1995, Journal of Materials Engineering and Performance.

[7]  D. R. Johnson,et al.  Processing and mechanical properties of in-situ composites from the NiAlCr and the NiAl(Cr,Mo) eutectic systems , 1995 .

[8]  D. Miracle Overview No. 104 The physical and mechanical properties of NiAl , 1993 .

[9]  R. Noebe,et al.  Physical and mechanical properties of the B2 compound NiAl , 1993 .

[10]  T. Sands,et al.  On the growth of NiAl intermetallics on III-V semiconductors , 1992 .

[11]  S. Raj,et al.  Correlation of deformation mechanisms with the tensile and compressive behavior of NiAl and NiAl(Zr) intermetallic alloys , 1992 .

[12]  K. Wandelt,et al.  Xenon adsorption on Al(110) , 1991 .

[13]  K. Wandelt,et al.  Two‐dimensional phase transition of adsorbed xenon on NiAl(110) and Al(110) , 1991 .

[14]  隆 渡辺,et al.  真空遮断器用Ni-Al-Cr電極材料の電気的特性 , 1991 .

[15]  K. Ishida,et al.  Ductility enhancement in NiAl (B2)-base alloys by microstructural control , 1991 .

[16]  I. Baker,et al.  Room temperature deformation behavior of multiphase Ni20at.%Al30at.%Fe and its constituent phases , 1991 .

[17]  S. Chambers,et al.  Schottky barrier height and thermal stability of the NiAl/n‐Ge/GaAs(001) interface , 1990 .

[18]  I. Baker,et al.  Room temperature tensile ductility in polycrystalline B2 Ni-30Al-20Fe , 1989 .

[19]  T. Sands Stability and epitaxy of NiAl and related intermetallic films on III‐V compound semiconductors , 1988 .

[20]  M. Wuttig,et al.  The adsorption of sulfur, carbon monoxide and oxygen on NiAl(111) , 1987 .

[21]  Lawrence H. Bennett,et al.  Binary alloy phase diagrams , 1986 .

[22]  John Aurie Dean,et al.  Lange's Handbook of Chemistry , 1978 .

[23]  A. J. Hickl,et al.  Kinetics of phase layer growth during aluminide coating of nickel , 1974 .

[24]  H. Jacobi,et al.  Defect structure in non-stoichiometric β-(Ni, Cu)Al , 1971 .

[25]  H. Cline,et al.  Structures, faults, and the rod-plate transition in eutectics , 1971 .

[26]  R. T. Pascoe,et al.  The Mechanical Behaviour of the Intermediate Phase NiAl , 1968 .

[27]  A. Ball,et al.  The deformation properties and electron microscopy studies of the intermetallic compound NiAl , 1966 .