Abstract Mechanical behaviour, tensile strength and failure modes in real unidirectional Kevlar/epoxy composites, loaded parallel to the fibres, at volume fraction (Vf) range 0.26–0.73, were investigated. It was found that the measured tensile strengths deviated from the expected values calculated from the Rule of Mixture. The deviation, which was minimal at Vf of about 0.5, was mainly due to geometrical deficiencies typical of real composites. At Vf 0.5 the deviation was explained by the increasing lack of matrix between some adjacent fibres and by squeezing of fibres. The initial part of loading was typified by straightening out of non-axial fibres, accompanied by fibre/matrix debonding. The straightening process was completed at a stress level of about 0.6–0.7 of the composite strength. Matrix damage began at this stress level and continued to develop up to final failure. Failure of Kevlar fibres was noted to occur only at an extremely short loading interval coinciding with the catastrophic final failure. This was due to the small scatter of Kevlar fibre strength.
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