First examples of six-coordinate niobium and tantalum homoleptic complexes with monodentate arenethiolate ligands. Synthesis and structural characterization of [Ph4P]2[Nb(SPh)6], Na(THF)3Nb(SPh-pMe)6. [(15-crown-5)Na][Ta(SPh)6], and Nb2(.mu.2-SPh)4(SPh)4(SPh)2Cl2(C2H5CN)2