Degradation transformation in spinel-type functional thick-film ceramic materials

Abstract The mathematical models of thermally-induced degradation processes in solids with nano- and microscale topological disordering – bulk and thick-film ceramic composites based on mixed transition-metal manganites are considered. It was shown that degradation transformations in these materials are best described by stretched or suppressed exponential relaxation function. The stretched exponential degradation kinetics is proper to own degradation transformations in such one-type systems as bulk ceramics and multilayered thick-film structures. The mechanism of degradation transformations in one-layered thick films, including two or more different on their origin elementary are described by suppressed exponential kinetics.

[1]  O. Shpotyuk,et al.  Controlled thermistor effect in the system CuxNi1–x–yCo2yMn2–yO4 , 2001 .

[2]  Michael W. Austin,et al.  Development of multi-functional sensors in thick-film and thin-film technology , 2000 .

[3]  P. Amstutz,et al.  New microwave applications for thick film thermistors , 1998 .

[4]  R. Legros,et al.  Aging study of nickel‐copper‐manganite negative temperature coefficient thermistors by thermopower measurements , 1992 .

[5]  Graham Williams,et al.  Non-symmetrical dielectric relaxation behaviour arising from a simple empirical decay function , 1970 .

[6]  H. Bau,et al.  Thick Film Thermistors Printed on Low Temperature Co-fired Ceramic Tapes , 2001 .

[7]  F. Kohlrausch.  Experimental-Untersuchungen über die elastische Nachwirkung bei der Torsion, Ausdehnung und Biegung , 1876 .

[8]  Á. Alegría,et al.  On the empirical functions describing the α-relaxation of glass-forming systems , 2001 .

[9]  A. Rousset,et al.  Intergranular phases in electroceramics , 1990 .

[10]  J. Deng,et al.  Integrated Thick-Film P-i-p+ Structures Based on Spinel Ceramics , 2012, 2012 IEEE International Conference on Oxide Materials for Electronic Engineering (OMEE).

[11]  O. Shpotyuk,et al.  Nanostructured oxyspinel multilayers for novel high-efficient conversion and control , 2014 .

[12]  R. Hilfer.  Analytical representations for relaxation functions of glasses , 2002 .

[13]  J. C. Phillips,et al.  Stretched exponential relaxation in molecular and electronic glasses , 1996 .

[14]  V. O. Balitska,et al.  On the analytical description of ageing kinetics in ceramic manganite-based NTC thermistors , 2002, Microelectron. Reliab..

[15]  O. Mazurin.  Relaxation phenomena in glass , 1977 .

[16]  B. Butkiewicz,et al.  Ageing behavior of electrical resistance in manganite NTC ceramics , 2004 .

[17]  O. Shpotyuk,et al.  Thick-film NTC thermistors based on spinel-type semiconducting electroceramics , 2004, 2004 24th International Conference on Microelectronics (IEEE Cat. No.04TH8716).

[18]  Bruno Morten,et al.  Thick-film sensors: an overview , 1986 .

[19]  N. White,et al.  Thick-film sensors : past, present and future , 1997 .

[20]  O. Shpotyuk,et al.  Integrated thick-film nanostructures based on spinel ceramics , 2014, Nanoscale Research Letters.

[21]  O. Shpotyuk,et al.  Sintering-modified mixed Ni–Co–Cu oxymanganospinels for NTC electroceramics , 2011 .

[22]  D. Belavic,et al.  LTCC resistors and resistive temperature sensors - chosen electrical and stability properties , 2005, 28th International Spring Seminar on Electronics Technology: Meeting the Challenges of Electronics Technology Progress, 2005..

[23]  L. Golonka,et al.  Thick-film resistive temperature sensors , 1997 .

[24]  Haim Eshach,et al.  The use of intuitive rules in interpreting students' difficulties in reading and creating kinematic graphs , 2014 .

[25]  O. Shpotyuk,et al.  Multilayer thick-film structures based on spinel ceramics1 , 2014 .

[26]  Haim H. Bau,et al.  Thick-film thermistors printed on LTCC tapes , 2001 .