Experimental Determination of Thermal Conductivity of Water−Agar Gel at Different Concentrations and Temperatures

Thermal conductivities of water−agar gels were determined at concentrations with mass fractions between w = 0.001 and w = 0.1 and temperatures from (278.15 to 323.15) K by means of a specifically designed probe system based on the line heat source principle. The thermal conductivity probe was calibrated and validated using glycerin (with mass fraction w = 0.99), glycol (with mass fraction w = 0.99), and ultra pure water (with resistivity 18.4 MΩ·cm, electric conductivity 0.055 μS·cm−1). Their measured and recommended values of thermal conductivity were in good agreement. The experimental data of thermal conductivity values of water−agar gels were sensitive to both concentration and temperature. The thermal conductivity of water−agar gels decreased with increasing concentration, while it increased as temperature increased. Predictive regression models were proposed to give a good fit for thermal conductivity with concentration and temperature.

[1]  C. G. Haugh,et al.  A Thermal Conductivity Probe for Small Food Samples , 1974 .

[2]  Songming Zhu,et al.  Evaluation and comparison of thermal conductivity of food materials at high pressure , 2008 .

[3]  E. Kolbe,et al.  Thermophysical properties of surimi paste at cooking temperature , 1997 .

[4]  Konstantinos Kakosimos,et al.  An Improved Application of the Transient Hot-Wire Technique for the Absolute Accurate Measurement of the Thermal Conductivity of Pyroceram 9606 up to 420 K , 2008 .

[5]  O. Miyawaki,et al.  Effective thermal diffusivity of food gels impregnated with air bubbles , 1999 .

[6]  K. Norton,et al.  The Probability Distribution of the Phase of the Resultant Vector Sum of a Constant Vector Plus a Rayleigh Distributed Vector , 1952 .

[7]  K. Nishinari,et al.  Differential scanning calorimetry, rheology, x-ray, and NMR of very concentrated agarose gels , 1989 .

[8]  A. Datta,et al.  Determination of specific heat and thermal conductivity of mushrooms (Pleurotus florida) , 1999 .

[9]  P. Andersson,et al.  Thermal conductivity of solids under pressure by the transient hot wire method , 1976 .

[10]  V. E. Sweat,et al.  Analysis of various design and operating parameters of the thermal conductivity probe , 1996 .

[11]  Laura J. Pyrak-Nolte,et al.  The effect of mixing conditions on the material properties of an agar gel—microstructural and macrostructural considerations , 2006 .

[12]  X. Ge,et al.  The measurement of thermal conductivities of solid fruits and vegetables , 1999 .

[13]  Shi-Ming Yang,et al.  AN EXPERIMENTAL STUDY OF NATURAL CONVECTION HEAT TRANSFER FROM A HORIZONTAL CYLINDER IN HIGH RAYLEIGH NUMBER LAMINAR AND TURBULENT REGIONS , 1994 .

[14]  J. Blackwell A Transient-Flow Method for Determination of Thermal Constants of Insulating Materials in Bulk Part I—Theory , 1954 .

[15]  Ashim K. Datta,et al.  Recommended design parameters for thermal conductivity probes for nonfrozen food materials , 1996 .

[16]  New thermal conductivity probe design based on the analysis of error sources , 2001 .

[17]  J. Blackwell THE AXIAL-FLOW ERROR IN THE THERMAL-CONDUCTIVITY PROBE , 1956 .

[18]  J. Blackwell,et al.  LETTERS TO THE EDITOR: Approximate Solution of a Transient Heat Flow Problem , 1951 .

[19]  Richard Griffiths,et al.  Analysis of thermal-probe measurements using an iterative method to give sample conductivity and diffusivity data , 2004 .

[20]  Kan-Ichi Hayakawa,et al.  Maximum Slope Method for Evaluating Thermal Conductivity Probe Data , 1993 .

[21]  Gang Zhao,et al.  An improved hot probe for measuring thermal conductivity of liquids , 2005 .

[22]  Liqun He,et al.  A dual-thermistor probe for absolute measurement of thermal diffusivity and thermal conductivity by the heat pulse method , 2003 .

[23]  F. Cherblanc,et al.  Electro-osmosis in gels: Application to Agar-Agar , 2008 .

[24]  Martin R. Okos,et al.  The Thermal Properties of Tomato Juice Concentrates , 1983 .

[25]  M. Djabourov,et al.  Small-angle X-ray scattering characterization of agarose sols and gels , 1989 .

[26]  K. Nishinari,et al.  RHEOLOGICAL PROPERTIES OF AQUEOUS AGAROSE‐GELATIN GELS , 1980 .