Ascorbic acid and copper in linoleate oxidation--Dunkley revisited.
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AbstractThe observation that reduced metals are more effective than the corresponding oxidised species in inducing peroxidation of linoleate underpins much of the study of metal-mediated lipid peroxidation which has taken place over the last 30 years. The four papers from the laboratory of WL Dunkley reviewed herein follow the observations of Ray et al.1 that the degradation of isolated serum lipoproteins was oxidative in nature and metal-ion-dependent.
[1] M. Freeman,et al. Ascorbic acid oxidation product(s) protect human low density lipoprotein against atherogenic modification. Anti- rather than prooxidant activity of vitamin C in the presence of transition metal ions. , 1993, The Journal of biological chemistry.
[2] D. Miller,et al. Studies of ascorbate-dependent, iron-catalyzed lipid peroxidation. , 1989, Archives of biochemistry and biophysics.
[3] H. Crespi,et al. Experiments on the Degradation of Lipoproteins from Serum , 1954 .