Transfer Layers: A Comparison across SWNTs, DWNTs, Graphite, and an Ionic Fluid

Lubrication is the science of friction at moving interfaces. Nanomaterials acting as interfacial modifiers can minimize friction and thereby improve energy efficiency. To test this hypothesis, single- (SWNT) and double-walled (DWNT) carbon nanotubes and an ionic fluid are tested individually and compared to SWNTs and graphite as additives within the ionic fluid. The minimum coefficient of friction is correlated with the longest lifetime using a ball-on-disc tribometer, in air, at atmospheric pressure. Results are interpreted in terms of the nanotubes' mechanical properties and the formation of transfer layers upon the tribosurfaces.

[1]  K. Miyoshi Solid Lubrication Fundamentals and Applications , 2019 .

[2]  V. Koch,et al.  Evaluation of Vapor Pressure and Ultra-High Vacuum Tribological Properties of Ionic Liquids , 2011 .

[3]  R. Ruoff,et al.  Chemical methods for the production of graphenes. , 2009, Nature nanotechnology.

[4]  M. Masuko,et al.  Tribological Characteristics of Imidazolium-based Room Temperature Ionic Liquids Under High Vacuum , 2007 .

[5]  Ichiro Minami,et al.  Effect and mechanism of additives for ionic liquids as new lubricants , 2007 .

[6]  M. Hasegawa,et al.  Radial deformation and stability of single-wall carbon nanotubes under hydrostatic pressure , 2006 .

[7]  Feng Zhou,et al.  Effect of the functional groups in ionic liquid molecules on the friction and wear behavior of aluminum alloy in lubricated aluminum-on-steel contact , 2005 .

[8]  R. Andrews,et al.  Solid lubrication by multiwalled carbon nanotubes in air and in vacuum , 2005 .

[9]  Zhi Yang,et al.  Modification of multi-walled carbon nanotubes with fatty acid and their tribological properties as lubricant additive , 2005 .

[10]  Kenneth W. Street,et al.  Friction properties of surface-fluorinated carbon nanotubes , 2005 .

[11]  A. Voevodin,et al.  Nanocomposite and nanostructured tribological materials for space applications , 2005 .

[12]  N. Fleischer,et al.  Ultralow-friction and wear properties of IF-WS2 under boundary lubrication , 2005 .

[13]  R. Hauert An overview on the tribological behavior of diamond-like carbon in technical and medical applications , 2004 .

[14]  Ali Erdemir,et al.  Genesis of superlow friction and wear in diamondlike carbon films , 2004 .

[15]  Qunji Xue,et al.  Room temperature ionic liquid 1-ethyl-3-hexylimidazolium-bis(trifluoromethylsulfonyl)-imide as lubricant for steel–steel contact , 2004 .

[16]  Dae-Soon Lim,et al.  Effect of Carbon Nanotube Addition on Tribological Behavior of UHMWPE , 2004 .

[17]  Mary C. Boyce,et al.  Mechanics of deformation of single- and multi-wall carbon nanotubes , 2004 .

[18]  M. Bermúdez,et al.  Friction and wear of aluminium–steel contacts lubricated with ordered fluids-neutral and ionic liquid crystals as oil additives , 2004 .

[19]  M. Marchetti,et al.  Evaluation of the Tribological behavior of Nano-Onions in Krytox 143AB , 2004 .

[20]  Gaorong Han,et al.  Tribological Behavior of Carbon-Nanotube-Filled PTFE Composites , 2003 .

[21]  V. C. Moore,et al.  Individually suspended single-walled carbon nanotubes in various surfactants , 2003 .

[22]  K. Liao,et al.  Nonlinear elastic properties of carbon nanotubes subjected to large axial deformations , 2002 .

[23]  R. D. Groot,et al.  University of Groningen Electronic structure of Cs 2 KSb and K 2 , 2002 .

[24]  Peng Wang,et al.  Tribological Performance of Room-Temperature Ionic Liquids as Lubricant , 2002 .

[25]  Dae-Soon Lim,et al.  Effect of carbon nanotube addition on the tribological behavior of carbon/carbon composites , 2002 .

[26]  Susan B. Sinnott,et al.  Tribological properties of carbon nanotube bundles predicted from atomistic simulations , 2001 .

[27]  X. B. Zhang,et al.  Tribological properties of carbon-nanotube-reinforced copper composites , 2001 .

[28]  W. Meng,et al.  Tribology of metal-containing diamond-like carbon coatings , 1997 .

[29]  A. Ball,et al.  The effect of transfer layers on the surface contact and wear of carbon-graphite materials , 1997 .

[30]  C. Langlade,et al.  New insights into adhesion and lubricating properties of graphite-based transfer films , 1994 .

[31]  D. Rigney,et al.  Sliding wear and transfer , 1983 .

[32]  W. 0. Winer Molybdenum disulfide as a lubricant: A review of the fundamental knowledge , 1967 .

[33]  P. Abel,et al.  Wear behavior of low-cost, lightweight TiC/Ti–6Al–4V composite under fretting: Effectiveness of solid-film lubricant counterparts , 2008 .

[34]  R. L. Wal,et al.  Application of Carbon Based Nano-Materials to Aeronautics and Space Lubrication , 2007 .

[35]  Zhaojie Cui,et al.  Friction and wear behaviors of ionic liquid of alkylimidazolium hexafluorophosphates as lubricants for steel/steel contact , 2004 .

[36]  Kenneth Holmberg,et al.  Coatings tribology—contact mechanisms and surface design , 1997 .

[37]  B. Bhushan,et al.  Handbook of Tribology: Materials, Coatings, and Surface Treatments , 1991 .