Preparation of Ultra-High Temperature Ceramics Based Materials by Sol-Gel Routes

Ultra‐high temperature ceramics (UHTCs) are a class of inorganic materials that have melt‐ ing point over 3000°C and are typically borides, carbides, and nitrides of early transition metals. UHTCs are considered as the promising candidate used in the extreme environ‐ ment involved with the hypersonic aviation thermal protective system. Synthesis of UHTC‐ based materials can be divided into solid‐based and solution‐based protocols according to the state of the raw materials. A sol‐gel technique is one of the solution‐based protocols for the preparation of UHTC‐based materials, which involves the hydrolysis, condensa‐ tion of the metal organic and/or metal inorganic compounds, gelation, and the posthigh temperature treatment of the dried gels. The sol‐gel technique enables the synthesis of UHTC‐based materials at 1300–1600°C. UHTC‐based materials with desired shapes, such as nanopowders, fibers, and porous monoliths, can also be prepared via sol‐gel routes.

[1]  G. Hilmas,et al.  Ultra-high temperature ceramics: Materials for extreme environments , 2017 .

[2]  J. Zou,et al.  Synthesis of ultra-refractory transition metal diboride compounds , 2016 .

[3]  R. M. Aghdam,et al.  Low Temperature Carbothermal Reduction Synthesis of ZrC Nanofibers Via Cyclized Electrospun PVP/Zr(OPr)4 Hybrid , 2016 .

[4]  Guo‐Jun Zhang,et al.  Syntheses of ZrC–SiC nanopowder via sol–gel method , 2016 .

[5]  R. M. Aghdam,et al.  Carbothermal reduction synthesis of ZrB2 nanofibers via pre-oxidized electrospun zirconium n-propoxide , 2015 .

[6]  Yanzi Gou,et al.  Synthesis and characterization of zirconium diboride precursor based on polycentric bridge bonds , 2015 .

[7]  Guo‐Jun Zhang,et al.  Preparation and characterization of stoichiometric zirconium carbide foams by direct foaming of zirconia sols , 2015, Journal of Porous Materials.

[8]  Zhehui Wang,et al.  Polyzirconosilane Preceramic Resin as Single Source Precursor of SiC–ZrC Ceramics , 2015, Journal of Inorganic and Organometallic Polymers and Materials.

[9]  Yanchun Zhou,et al.  Synthesis of ZrC–SiC Powders from Hybrid Liquid Precursors with Improved Oxidation Resistance , 2015 .

[10]  Guo‐Jun Zhang,et al.  Preparation of zirconium carbide foam by direct foaming method , 2014 .

[11]  Bala Vaidhyanathan,et al.  UHTC composites for hypersonic applications , 2014 .

[12]  Guo‐Jun Zhang,et al.  Fabrication of zirconium carbide nanofibers by electrospinning , 2014 .

[13]  T. Zhao,et al.  Synthesis, Characterization, and Microstructure of ZrC/SiC Composite Ceramics via Liquid Precursor Conversion Method , 2014 .

[14]  Erica L. Corral,et al.  Structural Influence on the Thermal Conversion of Self‐Catalyzed HfB2/ZrB2 Sol–Gel Precursors by Rapid Ultrasonication of Oxychloride Hydrates , 2014 .

[15]  Guo‐Jun Zhang,et al.  Synthesis of ZrB2 nanofibers by carbothermal reduction via electrospinning , 2013 .

[16]  T. Zhao,et al.  Synthesis of ZrC–SiC Powders by a Preceramic Solution Route , 2013 .

[17]  T. Zhao,et al.  Synthesis, Characterization, and Microstructure of Hafnium Boride‐Based Composite Ceramics Via Preceramic Method , 2013 .

[18]  T. Zhao,et al.  Synthesis of soluble poly-yne polymers containing zirconium and silicon and corresponding conversion to nanosized ZrC/SiC composite ceramics. , 2013, Dalton transactions.

[19]  刘丹,et al.  Synthesis of soluble poly-yne polymers containing zirconium and silicon and corresponding conversion to nanosized ZrC/SiC composite ceramics , 2013 .

[20]  A. Jankowiak,et al.  Ultra High Temperature Ceramics : Densification, Properties and Thermal Stability. , 2011 .

[21]  Jun-ping Li,et al.  Morphology evolution of ZrB2 nanoparticles synthesized by sol–gel method , 2011 .

[22]  Jun-ping Li,et al.  Synthesis of ZrB2 nanoparticles by sol-gel method , 2011 .

[23]  Ju Feng,et al.  Synthesis of ZrB 2 nanoparticles by sol-gel method , 2011 .

[24]  Paolo Colombo,et al.  Polymer‐Derived Ceramics: 40 Years of Research and Innovation in Advanced Ceramics , 2010 .

[25]  T. Zhao,et al.  Synthesis of nanosized zirconium carbide from preceramic polymers by the facile one‐pot reaction , 2010 .

[26]  Jae Yeol Lee,et al.  Fabrication and characterization of zirconium carbide (ZrC) nanofibers with thermal storage property , 2009 .

[27]  B. Clauss Fibers for Ceramic Matrix Composites , 2008 .

[28]  Jae Yeol Lee,et al.  Fabrication of zirconium carbide (ZrC) ultra-thin fibers by electrospinning , 2008 .

[29]  Anubhav Jain,et al.  Solution–Based Processing of Nanocrystalline ZrC , 2008 .

[30]  Zheng-ren Huang,et al.  Carbothermal synthesis of ultra-fine zirconium carbide powders using inorganic precursors via sol–gel method , 2007 .

[31]  William G. Fahrenholtz,et al.  Refractory Diborides of Zirconium and Hafnium , 2007 .

[32]  D. Gosset,et al.  Synthesis of nanosized zirconium carbide by a sol-gel route , 2007 .

[33]  E. Opila,et al.  UHTCs: Ultra-High Temperature Ceramic Materials for Extreme Environment Applications , 2007 .

[34]  André R. Studart,et al.  Processing Routes to Macroporous Ceramics: A Review , 2006 .

[35]  Younan Xia,et al.  Electrospinning: A Simple and Versatile Technique for Producing Ceramic Nanofibers and Nanotubes , 2006 .

[36]  Carlos R. Rambo,et al.  Manufacturing of biomorphic (Si,Ti,Zr)-carbide ceramics by sol–gel processing , 2005 .

[37]  Anubhav Jain,et al.  Carbothermal reduction synthesis of nanocrystalline zirconium carbide and hafnium carbide powders using solution-derived precursors , 2004 .

[38]  J. Spain,et al.  Designing for ultrahigh-temperature applications: The mechanical and thermal properties of HfB2, HfCx, HfNx and αHf(N) , 2004 .

[39]  Younan Xia,et al.  Electrospinning of Nanofibers: Reinventing the Wheel? , 2004 .

[40]  E. Bernardo,et al.  Macro- and micro-cellular porous ceramics from preceramic polymers , 2003 .

[41]  I. Hasegawa,et al.  Inorganic–organic hybrid route to synthesis of ZrC and Si–Zr–C fibres , 1999 .

[42]  H. Preiss,et al.  Synthesis of polymeric titanium and zirconium precursors and preparation of carbide fibres and films , 1998 .

[43]  A. Pierre,et al.  Introduction to Sol-Gel Processing , 1998 .

[44]  H. Tomioka,et al.  Preparation of continuous zirconia fibres from polyzirconoxane synthesized by the facile one-pot reaction , 1998 .

[45]  L. Berger,et al.  Thermal treatment of binary carbonaceous/ zirconia gels and formation of Zr(C,O,N) solid solutions , 1996 .

[46]  T. Gunji,et al.  A one-pot synthesis of polyzirconoxane as a precursor for continuous zirconia fibres , 1994 .

[47]  G. C. Wall THE SOL-GEL PROCESS , 1965 .