Interactions between cyanoborohydrides and (bis(diphenylphosphino)methane)dichloroplatinum. X-ray structural characterization of the complexes [Pt(dppm)(CNBH2CN)]2.cntdot.CHCl3, [Pt(dppm)(CN)]2.cntdot.1/2C5H5N, and [Pt(dppm)(CNBH3)]2.cntdot.H2O. Isomerization of trans-[Pt(dppm)(NCBH2CN)]2 to trans-[

A series of complexes [Pt(dppm)L] 2 (L=NCBH 3 , NCBH 2 CN, CNBH 2 CN, CN, CNBH 3 ), have been prepared from NaBH 3 CN or NaBH 2 (CN) 2 and Cl 2 Pt II (dppm) or [Pt I (dppm)Cl] 2 . The particular complex or linkage isomer obtained is dependent on the choice of solvent. X-ray structural characterizations have been performed