Si-Ion Implantation Doping in β-Ga2O3 and Its Application to Fabrication of Low-Resistance Ohmic Contacts

We developed a donor doping technique for β-Ga2O3 by using Si-ion (Si+) implantation. For the implanted Ga2O3 substrates with Si+=1×1019–5×1019 cm-3, a high activation efficiency of above 60% was obtained after annealing in a nitrogen gas atmosphere at a relatively low temperature of 900–1000 °C. Annealed Ti/Au electrodes fabricated on the implanted Ga2O3 layers showed ohmic behavior. The Ga2O3 with Si+=5×1019 cm-3 showed the lowest specific contact resistance and resistivity obtained in this work of 4.6×10-6 Ωcm2 and 1.4 mΩcm, respectively.

[1]  F. Recht,et al.  Nonalloyed ohmic contacts in AlGaN/GaN HEMTs by ion implantation with reduced activation annealing temperature , 2006, IEEE Electron Device Letters.

[2]  Kiyoshi Shimamura,et al.  Electrical conductivity and carrier concentration control in β-Ga2O3 by Si doping , 2008 .

[3]  R. F. Karlicek,et al.  Electrical and structural analysis of high-dose Si implantation in GaN , 1997 .

[4]  Hideo Aida,et al.  Growth of β-Ga2O3 Single Crystals by the Edge-Defined, Film Fed Growth Method , 2008 .

[5]  R. Opila,et al.  Dielectric properties of electron‐beam deposited Ga2O3 films , 1994 .

[6]  Kazuo Nakajima,et al.  Fabrication and characterization of transparent conductive Sn-doped β-Ga2O3 single crystal , 2007 .

[7]  Akito Kuramata,et al.  Device-Quality β-Ga2O3 Epitaxial Films Fabricated by Ozone Molecular Beam Epitaxy , 2012 .

[8]  B. J. Baliga,et al.  Power semiconductor device figure of merit for high-frequency applications , 1989, IEEE Electron Device Letters.

[9]  Akito Kuramata,et al.  Gallium oxide (Ga2O3) metal-semiconductor field-effect transistors on single-crystal β-Ga2O3 (010) substrates , 2012 .

[10]  James A. Fellows,et al.  Electrical activation studies of GaN implanted with Si from low to high dose , 2002 .

[11]  T. Kimoto,et al.  Nitrogen Ion Implantation into α‐SiC Epitaxial Layers , 1997 .

[12]  H. H. Tippins Optical Absorption and Photoconductivity in the Band Edge of β − Ga 2 O 3 , 1965 .

[13]  H. Dunlap,et al.  DIODES IN SILICON CARBIDE BY ION IMPLANTATION , 1969 .

[14]  Takayoshi Oshima,et al.  Atomically controlled surfaces with step and terrace of β-Ga2O3 single crystal substrates for thin film growth , 2008 .

[15]  Hideo Hosono,et al.  Synthesis and control of conductivity of ultraviolet transmitting β-Ga2O3 single crystals , 1997 .

[16]  John C. Zolper,et al.  Ion implantation doping and isolation of GaN , 1995 .

[17]  Noboru Ichinose,et al.  Large-size β-Ga2O3 single crystals and wafers , 2004 .

[18]  H. Matsunami,et al.  Electronic behaviors of high-dose phosphorus-ion implanted 4H-SiC(0001) , 2004 .