Pressureless densification and properties of TiB 2 –B 4 C composite ceramics with Ni as additives

Titanium diboride-boron carbide (TiB 2 -B 4 C) composite ceramics were prepared using different amounts of Ni as sintering aids by pressureless sintering at 2100°C for 60 min under an argon atmosphere. This study focused on the effects of different amounts of Ni as additives on densification and mechanical and thermal properties of TiB 2 -B 4 C composite ceramics. Results showed that the relative density, hardness, flexural strength and thermal conductivity of obtained composite ceramics with 1.3 wt% Ni addition were 98%, 20.4 GPa, 330 MPa and 30 W/m K, respectively. However, fracture toughness was 6 MPa m 1/2 when the content of Ni was fixed at 2.2 wt%.

[1]  Y. Sakka,et al.  Ultra-high elevated temperature strength of TiB2-based ceramics consolidated by spark plasma sintering , 2017 .

[2]  H. Baharvandi,et al.  Effect of different additives on the sintering ability and the properties of B4C–TiB2 composites , 2015 .

[3]  H. Baharvandi,et al.  Effect of TiO2 nanoparticles on the pressureless sintering of B4C–TiB2 nanocomposites , 2015 .

[4]  K. Sairam,et al.  Hot-pressing of MoSi2 reinforced B4C composites , 2014 .

[5]  R. White,et al.  Mechanical properties and deformation mechanisms of B4C–TiB2 eutectic composites , 2014 .

[6]  Chuanzhen Huang,et al.  Effects of TiC content and melt phase on microstructure and mechanical properties of ternary TiB2-based ceramic cutting tool materials , 2014 .

[7]  Chuanzhen Huang,et al.  Microstructure and mechanical properties of TiB2–SiC ceramic composites by Reactive Hot Pressing , 2014 .

[8]  D. Agrawal,et al.  Tough ceramics by microwave sintering of nanocrystalline titanium diboride ceramics , 2014 .

[9]  V. Sglavo,et al.  Pressureless sintering of B4C–TiB2 composites with Al additions , 2011 .

[10]  K. Vanmeensel,et al.  Microstructure and mechanical properties of pulsed electric current sintered B4C-TiB2 composites , 2011 .

[11]  L. Pei,et al.  B4C/TiB2 composite powders prepared by carbothermal reduction method , 2009 .

[12]  W. Baowei Effect of Mechanical Properties on Erosion Resistances of B_4C/TiB_2 Matrix Ceramic Nozzles , 2009 .

[13]  R. Haas,et al.  Solid-state properties of hot-pressed TiB2 ceramics , 2005 .

[14]  S. Kanzaki,et al.  High strength B4C–TiB2 composites fabricated by reaction hot-pressing , 2003 .

[15]  S. Kanzaki,et al.  B4C−CrB2 composites with improved mechanical properties , 2003 .

[16]  Hyoun‐Ee Kim,et al.  Sintering and mechanical properties of titanium diboride with aluminum nitride as a sintering aid , 2002 .

[17]  A. Bellosi,et al.  Production and Characteristics of B4C/TiB2 Composites , 1995 .