Induced growth of asymmetric nanocantilever arrays on polar surfaces.

We report that the Zn-terminated ZnO (0001) polar surface is chemically active and the oxygen-terminated (000(-)1) polar surface is inert in the growth of nanocantilever arrays. Longer and wider "comblike" nanocantilever arrays are grown from the (0001)-Zn surface, which is suggested to be a self-catalyzed process due to the enrichment of Zn at the growth front. The chemically inactive (0001;)-O surface typically does not initiate any growth, but controlling experimental conditions could lead to the growth of shorter and narrower nanocantilevers from the intersections between (000(-)1)-O with +/- (01(-)10) surfaces.

[1]  T. Sabine,et al.  The wurtzite Z parameter for beryllium oxide and zinc oxide , 1969 .

[2]  G. Thornton,et al.  Stability of polar oxide surfaces. , 2001, Physical review letters.

[3]  Density-functional study of the structure and stability of ZnO surfaces , 2002, cond-mat/0206549.

[4]  G. Thornton,et al.  Orientation of Benzene and Phenoxy on the Polar ZnO(0001)−Zn Surface† , 2001 .

[5]  Olga Dulub,et al.  Novel stabilization mechanism on polar surfaces: ZnO(0001)-Zn. , 2003, Physical review letters.

[6]  J. C. H. Spence,et al.  Electron Microdiffraction , 2020, Springer US.

[7]  O. Dulub STM Study of the Geometric and Electronic Structure of ZnO (0001)-Zn, (0001bar)-O, (101bar 0), and (1120bar) Surfaces , 2002 .

[8]  P. W. Tasker,et al.  The stability of ionic crystal surfaces , 1979 .

[9]  Zhong Lin Wang,et al.  Nanobelts of Semiconducting Oxides , 2001, Science.

[10]  John B. Shoven,et al.  I , Edinburgh Medical and Surgical Journal.

[11]  Phaedon Avouris,et al.  Field-Effect Transistors Based on Single Semiconducting Oxide Nanobelts , 2003 .

[12]  C. Quate,et al.  Parallel atomic force microscopy using cantilevers with integrated piezoresistive sensors and integrated piezoelectric actuators , 1995 .

[13]  L. N. Demianets,et al.  Mechanism of growth of ZnO single crystals from hydrothermal alkali solutions , 2002 .

[14]  D. Marx,et al.  Stabilization of polar ZnO surfaces: validating microscopic models by using CO as a probe molecule. , 2003, Physical review letters.

[15]  Andrew G. Glen,et al.  APPL , 2001 .

[16]  G. Meng,et al.  Ordered semiconductor ZnO nanowire arrays and their photoluminescence properties , 2000 .

[17]  S. Vézian,et al.  Defect characterization in ZnO layers grown by plasma-enhanced molecular-beam epitaxy on (0001) sapphire substrates , 2001 .