Sensitivity study of pulsed neutron-gamma saturation monitoring at the Altmark site in the context of CO2 storage

The injection of CO2 into depleted natural gas reservoirs has been proposed as a promising new technology for combining enhanced gas recovery and geological storage of CO2. During the injection, application of suitable techniques for monitoring of the induced changes in the subsurface is required. Observing the movement and the changes in saturation of the fluids contained in the reservoir and the confining strata is among the primary aims here. It is shown that under conditions similar to the Altmark site, Germany, pulsed neutron-gamma logging can be applied with limitations. The pulsed neutron-gamma method can be applied for detection and quantification of changes in brine saturation and water content, whereas changes in the gas composition are below the detection limit. A method to account for the effects of salt precipitation resulting from evaporation of residual brine is presented.

[1]  B. Metz IPCC special report on carbon dioxide capture and storage , 2005 .

[2]  Ton Wildenborg,et al.  Underground geological storage , 2005 .

[3]  Terizhandur S. Ramakrishnan,et al.  Time-lapse carbon dioxide monitoring with pulsed neutron logging , 2007 .

[4]  David W. Keith,et al.  Sensitivity Analysis of Salt Precipitation and CO2-Brine Displacement in Saline Aquifers , 2009 .

[5]  Curtis M. Oldenburg,et al.  Economic feasibility of carbon sequestration with enhanced gas recovery (CSEGR) , 2004 .

[6]  Olaf Kolditz,et al.  CLEAN: project overview on CO2 large-scale enhanced gas recovery in the Altmark natural gas field (Germany) , 2012, Environmental Earth Sciences.

[7]  Karsten Pruess,et al.  Formation dry‐out from CO2 injection into saline aquifers: 1. Effects of solids precipitation and their mitigation , 2009 .

[8]  Y. Wang,et al.  HALITE PRECIPITATION AND PERMEABILITY ASSESSMENT DURING SUPERCRITICAL CO 2 CORE FLOOD , 2010 .

[9]  Susan D. Hovorka,et al.  Monitoring saturation changes for CO2 sequestration : Petrophysical support of the frio brine pilot experiment , 2006 .

[10]  Dirk Schäfer,et al.  CLEAN: Preparing for a CO2 -based enhanced gas recovery in a depleted gas field in Germany , 2011 .

[11]  S. J. Kimminau,et al.  The Design of Pulsed Neutron Reservoir Monitoring Programs , 1992 .

[12]  O. Serra,et al.  Fundamentals of well-log interpretation , 1984 .

[13]  Charles W. Morris,et al.  Reservoir Monitoring with Pulsed Neutron Capture Logs , 2005 .

[14]  V. F. Sears Neutron scattering lengths and cross sections , 1992 .

[15]  M. G. Portal,et al.  Improved pulsed neutron capture logging with slim carbon-oxygen tools: Methodology , 1995 .

[16]  M. J. van der Burgt,et al.  Carbon dioxide disposal from coal-based IGCC's in depleted gas fields , 1992 .

[17]  W. Kleinitz,et al.  The Precipitation of Salt in Gas Producing Wells , 2001 .

[18]  Darwin V. Ellis,et al.  Well Logging for Earth Scientists , 1987 .

[19]  Sebastian Bauer,et al.  Modelling CO2-induced fluid–rock interactions in the Altensalzwedel gas reservoir. Part II: coupled reactive transport simulation , 2012, Environmental Earth Sciences.

[20]  K. Pruess,et al.  The simulator TOUGH2/EWASG for modelling geothermal reservoirs with brines and non-condensible gas , 1997 .

[21]  Alfredo Battistelli,et al.  2D modeling of salt precipitation during the injection of dry CO2 in a depleted gas reservoir , 2007 .

[22]  Oliver C. Mullins,et al.  Quantification of carbon dioxide using downhole Wireline formation tester measurements , 2006 .

[23]  Sebastian Bauer,et al.  Modelling CO2-induced fluid–rock interactions in the Altensalzwedel gas reservoir. Part I: from experimental data to a reference geochemical model , 2012, Environmental Earth Sciences.

[24]  Allen M. Rowe,et al.  Pressure-volume-temperature-concentration relation of aqueous sodium chloride solutions , 1970 .

[25]  Jim J. Smolen,et al.  Cased hole and production log evaluation , 1996 .