A techno-economic analysis of microalgae remnant catalytic pyrolysis and upgrading to fuels

Abstract Microalgae have been proposed as potentially promising feedstock for the production of renewable transportation fuels. The plants are intriguing for their capacity to serve both as a source of renewable carbon fuels and as a powerful tool for carbon sequestration. Microalgae remnant, a low-cost by-product of microalgae lipid extraction, is a particularly appealing candidate for these processes. Through catalytic pyrolysis, microalgae remnant is capable of producing aromatic hydrocarbons that could be used for the production of drop-in biofuels. One of the most challenging barriers to this promising pathway is the high moisture content of harvested microalgae. The goal of this study is to compare the economics of two catalytic pyrolysis pathways for the production of drop-in biofuels, each pathway employing its own distinct method of feedstock dewatering: thermal drying or partial mechanical dewatering. The study presents chemical process models, capital expense and operating cost estimates, and sensitivity analyses of both scenarios. Results indicate that thermal drying prior to catalytic pyrolysis (TDCP) incurs capital costs similar to those incurred in partial mechanical dewatering prior to catalytic pyrolysis (MDCP) ($346 million vs. $409 million). TDCP and MDCP yield minimum fuel-selling prices (MFSPs) of $1.80/l and $1.49/l, respectively. Energy analysis shows that TDCP achieves 16.8% energy efficiency and MDCP achieves 26.7% efficiency.

[1]  Tristan R. Brown,et al.  Techno-economic analysis of biomass to transportation fuels and electricity via fast pyrolysis and hydroprocessing , 2013 .

[2]  Robert J. Evans,et al.  Hydrogen from biomass-production by steam reforming of biomass pyrolysis oil ☆ , 2007 .

[3]  Andre M. Coleman,et al.  Renewable Diesel from Algal Lipids: An Integrated Baseline for Cost, Emissions, and Resource Potential from a Harmonized Model , 2012 .

[4]  Robert C. Brown,et al.  Catalytic pyrolysis of microalgae for production of aromatics and ammonia , 2013 .

[5]  Jacob A. Moulijn,et al.  Catalytic pyrolysis of microalgae to high-quality liquid bio-fuels , 2011 .

[6]  S. Polasky,et al.  Environmental, economic, and energetic costs and benefits of biodiesel and ethanol biofuels. , 2006, Proceedings of the National Academy of Sciences of the United States of America.

[7]  Yihua Li,et al.  Mild catalytic pyrolysis of biomass for production of transportation fuels: a techno-economic analysis , 2014 .

[8]  Phillip E. Savage,et al.  Characterization of Product Fractions from Hydrothermal Liquefaction of Nannochloropsis sp. and the Influence of Solvents , 2011 .

[9]  Klaus D. Timmerhaus,et al.  Plant design and economics for chemical engineers , 1958 .

[10]  Daren E. Daugaard,et al.  Techno-Economic Analysis of Biomass Fast Pyrolysis to Transportation Fuels , 2010 .

[11]  Sally L. Homsy,et al.  Fast pyrolysis of microalgae remnants in a fluidized bed reactor for bio-oil and biochar production. , 2013, Bioresource technology.

[12]  Michael J. Haas,et al.  Simplifying biodiesel production: The direct or in situ transesterification of algal biomass , 2011 .

[13]  J. R. Hess,et al.  Process Design and Economics for Conversion of Lignocellulosic Biomass to Ethanol , 2011 .

[14]  Nigel W.T. Quinn,et al.  A Realistic Technology and Engineering Assessment of Algae Biofuel Production , 2010 .

[15]  Tristan R. Brown,et al.  Techno‐economic analysis of biobased chemicals production via integrated catalytic processing , 2012 .

[16]  W. Green,et al.  Investigating the techno‐economic trade‐offs of hydrogen source using a response surface model of drop‐in biofuel production via bio‐oil upgrading , 2012 .

[17]  S. Adhikari,et al.  Catalytic pyrolysis of green algae for hydrocarbon production using H+ZSM-5 catalyst. , 2012, Bioresource technology.