论文信息 - {μ-[2-(Dimethylamino)phenyl](2-fluorophenyl)methanolato}pentamethyldialuminum(III)

{μ-[2-(Dimethylamino)phenyl](2-fluorophenyl)methanolato}pentamethyldialuminum(III)

Each of the Al atoms in the title compound, [Al2(CH3)5(C15H15FNO)], is four-coordinated in a distorted tetrahedral geometry. The dimethylaluminium centre is bound by the N and the O atoms of the (2-dimethylaminophenyl)(2-fluorophenyl)methanolate ligand. The second Al atom is bound by the methanolate O atom and by three methyl C atoms. The crystal studied was a racemic twin with a 0.4 (2):0.6 (2) domain ratio.

[1] D. Atwood,et al. Group 13 compounds incorporating Salen ligands. , 2001, Chemical reviews.

[2] J. Sieler,et al. Synthesis and molecular structures of (2-dialkylaminophenyl)alcohols and of 2-phenylaminoalkyl-dimethylaminobenzene derivatives , 2004 .

[3] N. Nomura,et al. Salicylaldimine-Aluminum Complexes for the Facile and Efficient Ring-Opening Polymerization of ∊-Caprolactone , 2005 .

[4] Odile Dechy-Cabaret,et al. Controlled ring-opening polymerization of lactide and glycolide. , 2004, Chemical reviews.

[5] G. Sheldrick. A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[6] D. Atwood,et al. Unusual dicationic trimetallic aluminum chelates , 2000 .

[7] K. Izod. Complexes of P-stabilised carbanions with s- and p-elements , 2002 .

[8] D. J. Linton,et al. Group 12 and heavier Group 13 alkali metal 'ate complexes , 2001 .